A copper-catalyzed arylation/nucleophilic addition/fragmentation/C–S bond formation cascade: synthesis of bis(arylthio)imines

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发布日期 2017-01-03

DOI 10.1039/C6QO00739B

影响因子 5.281

作者

Wei-Si Guo, Yuan-Chao Wang, Qian Dou, Li-Rong Wen, Ming Li

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摘要

A new tandem arylation/nucleophilic addition/fragmentation/C–S bond formation reaction involving diaryliodonium salts as electrophiles was developed with Cu(OTf)2 as the catalyst. A series of unexpected bis(arylthio)imine derivatives were generated in good yields. The reaction proceeds under mild conditions, and the bis(arylthio)imines are readily transformed to other useful products.

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来源期刊

Organic Chemistry Frontiers

CiteScore: 7.8

自引率: 8.7%

年发文量: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

A copper-catalyzed arylation/nucleophilic addition/fragmentation/C–S bond formation cascade: synthesis of bis(arylthio)imines

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