Ring-opening selenation of cyclobutanols: synthesis of γ-selenylated alkyl ketones through C–C bond cleavage

文献信息

发布日期 2016-12-21

DOI 10.1039/C6QO00744A

影响因子 5.281

作者

Mingyang Wang, Zhen Wu

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摘要

An efficient and practical manganese-mediated ring-opening selenation of cyclobutanols is disclosed. The transformation has broad functionality tolerance, producing a variety of γ-selenylated alkyl ketones in synthetically useful yields. Mechanistically, the radical-promoted regioselective cyclic C–C bond cleavage and sp3 C–Se bond formation are involved.

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来源期刊

Organic Chemistry Frontiers

CiteScore: 7.8

自引率: 8.7%

年发文量: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Ring-opening selenation of cyclobutanols: synthesis of γ-selenylated alkyl ketones through C–C bond cleavage

文献信息

期刊推荐

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