Bubble nucleation and growth in nanochannels
文献信息
Bo Bao, Seyed Hadi Zandavi, Huawei Li, Junjie Zhong, Arnav Jatukaran, Farshid Mostowfi, David Sinton
We apply micro- and nanofluidics to study fundamental phase change behaviour at nanoscales, as relevant to shale gas/oil production. We investigate hydrocarbon phase transition in sub-100 nm channels under conditions that mimic the pressure drawdown process. Measured cavitation pressures are compared with those predicted from the nucleation theory. We find that cavitation pressure in the nanochannels corresponds closer to the spinodal limit than that predicted from classical nucleation theory. This deviation indicates that hydrocarbons remain in the liquid phase in nano-sized pores under pressures much lower than the saturation pressure. Depending on the initial nucleation location – along the channel or at the end – two types of bubble growth dynamics were observed. Bubble growth was measured experimentally at different nucleation conditions, and results agree with a fluid dynamics model including evaporation rate, instantaneous bulk liquid velocity, and bubble pressure. Collectively these results demonstrate, characterize, and quantify isothermal bubble nucleation and growth of a pure substance in nanochannels.
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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.










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