Electron-triggered chemistry in HNO3/H2O complexes
文献信息
Milan Ončák, Juraj Fedor, Jaroslav Kočišek, Andriy Pysanenko, Martin K. Beyer, Michal Fárník
Polar stratospheric clouds, which consist mainly of nitric acid containing ice particles, play a pivotal role in stratospheric chemistry. We investigate mixed nitric acid–water clusters (HNO3)m(H2O)n, m ≈ 1–6, n ≈ 1–15, in a laboratory molecular beam experiment using electron attachment and mass spectrometry and interpret our experiments using DFT calculations. The reactions are triggered by the attachment of free electrons (0–14 eV) which leads to subsequent intracluster ion–molecule reactions. In these reactions, the nitrate anion NO3− turns out to play the central role. This contradicts the electron attachment to the gas-phase HNO3 molecule, which leads almost exclusively to NO2−. The nitrate containing clusters are formed through at least three different reaction pathways and represent terminal product ions in the reaction cascade initiated by the electron attachment. Besides, the complex reaction pathways represent a new hitherto unrecognized source of atmospherically important OH and HONO molecules.
期刊推荐

Herald of the Russian Academy of Sciences

Acta Metallurgica Sinica-English Letters

Journal of Asian Natural Products Research

Journal of the Indian Institute of Science

Bioorganic & Medicinal Chemistry

Biocatalysis and Biotransformation

Chinese Journal of Chemistry

Cellulose

Bioorganic & Medicinal Chemistry Letters

Topics in Catalysis
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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.


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