Investigation of the surface plasmon polariton and electrochemical properties of covalent and non-covalent functionalized reduced graphene oxide

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发布日期 2017-10-06
DOI 10.1039/C7CP05923J
影响因子 3.676
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摘要

The surface electronic properties of graphene oxide (GO) were modified through reduction and functionalization. Non-covalent functionalization was found to be superior compared to covalent functionalization due to the formation of few-layer graphene with a low defect content and average crystalline length. Because of the restoration of sp2 hybridization, non-covalently functionalized reduced graphene oxide (rGO) showed a better plasmonic response compared to GO, rGO and covalently functionalized rGO. Due to the available π electrons from the sp2 network of graphene as well as surface functionality, non-covalent functionalized rGO exhibited elevated donor density. Furthermore, due to the synergistic effect of surface electronic properties as well as adsorption and recombination at the barrier, superior charge transfer was achieved at the electrode–electrolyte interface for non-covalent functionalized rGO.

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来源期刊

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
自引率: 10.3%
年发文量: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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