Selective C–H bond electro-oxidation of benzylic acetates and alcohols to benzaldehydes

文献信息

发布日期 2017-11-14

DOI 10.1039/C7OB02300F

影响因子 3.876

作者

Alan M. Jones

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摘要

A chemical oxidant-free and mediator-free, direct electro-oxidation of both benzylic alcohols and benzylic esters are reported. The scope of the reaction is explored as a function of both steric and electronic effects. Expansion of the scope to non-benzylic and heteroaryl substrates is investigated. Functionalisation of esters and alcohols selectively to the aldehyde oxidation level using a traceless electron approach is reported.

期刊推荐

New Journal of Chemistry

Acta Materialia

Saudi Pharmaceutical Journal

Crystallography Reports

Chemistry Education Research and Practice

Current Opinion in Colloid & Interface Science

Journal of Natural Medicines

Current Opinion in Solid State & Materials Science

Chemical Communications

Journal of Saudi Chemical Society

来源期刊

Organic & Biomolecular Chemistry

CiteScore: 3.4

自引率: 10.3%

年发文量: 1041

Organic & Biomolecular Chemistry (OBC) publishes original and high impact research and reviews in organic chemistry. We welcome research that shows new or significantly improved protocols or methodologies in total synthesis, synthetic methodology or physical and theoretical organic chemistry as well as research that shows a significant advance in the organic chemistry or molecular design aspects of chemical biology, catalysis, supramolecular and macromolecular chemistry, theoretical chemistry, mechanism-oriented physical organic chemistry, medicinal chemistry or natural products. Articles published in the journal should report new work which makes a highly-significant impact in the field. Routine and incremental work is generally not suitable for publication in the journal. More details about key areas of our scope are below. In all cases authors should include in their article clear rationale for why their research has been carried out.

Selective C–H bond electro-oxidation of benzylic acetates and alcohols to benzaldehydes

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Organic & Biomolecular Chemistry

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