Olefin cross metathesis and ring-closing metathesis in polymer chemistry

文献信息

发布日期 2017-04-24

DOI 10.1039/C7PY00340D

影响因子 5.582

作者

Fern Sinclair, Joëlle Prunet, Michael P. Shaver

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摘要

The use of olefin cross metathesis in preparing functional polymers, through either pre-functionalisation of monomers or post-polymerisation functionalisation is growing in both scope and breadth. The broad functional group tolerance of olefin metathesis offers a wealth of opportunities for introducing a broad range of functional groups into the polymer backbone, tuning polymer properties and expanding potential applications. Similarly, ring-closing metathesis offers the ability to tune the polymer macrostructure and microstructure to similar effect. In this review, we explore the importance of understanding selectivity in olefin cross metathesis in designing functional polymers, the manipulation of this reactivity to prepare (multi)functional polymers, and show how polymer systems can be constructed to favour ring closing and change backbone structure and properties.

期刊推荐

Chemical Papers

Heterocycles

Fire Safety Journal

Corrosion Reviews

Composite Structures

Chemistry Letters

Journal of the Royal Society of New Zealand

Organometallics

Experimental Techniques

Geotextiles and Geomembranes

来源期刊

Polymer Chemistry

CiteScore: 8.6

自引率: 7.3%

年发文量: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Olefin cross metathesis and ring-closing metathesis in polymer chemistry

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来源期刊

Polymer Chemistry

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