Rhodium-catalyzed denitrogenative transannulation of 1,2,3-triazolyl-carbamates: efficient access to 4-aminooxazolidinones

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发布日期 2017-04-17

DOI 10.1039/C7QO00101K

影响因子 5.281

作者

Kuntal Pal, Chandra M. R. Volla

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摘要

Herein we describe a novel Rh(II)-catalyzed intramolecular transannulation reaction of 1,2,3-triazolyl carbamates to access functionalized 4-aminooxazolidinones under operationally simple conditions with low catalyst loadings. A one-pot tandem Cu(I)-catalyzed synthesis of 1,2,3-triazolyl-carbamates from propargyl carbamates followed by their rearrangement/cyclization with Rh(II)-carboxylates was also presented.

期刊推荐

Medicinal Chemistry Research

Bioorganic & Medicinal Chemistry

Journal of Chemical Sciences

Electroanalysis

Topics in Catalysis

Chinese Journal of Chemistry

Heteroatom Chemistry

Journal of Asian Natural Products Research

Cellulose

Polycyclic Aromatic Compounds

来源期刊

Organic Chemistry Frontiers

CiteScore: 7.8

自引率: 8.7%

年发文量: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Rhodium-catalyzed denitrogenative transannulation of 1,2,3-triazolyl-carbamates: efficient access to 4-aminooxazolidinones

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