Robust, non-fouling liters-per-day flow synthesis of ultra-small catalytically active metal nanoparticles in a single-channel reactor
文献信息
Wai Kuan Wong, Swee Kun Yap, Yi Chen Lim, Saif A. Khan, Frédéric Pelletier, Elena Cristina Corbos
In this communication, we demonstrate the robust, non-fouling continuous synthesis of catalytically active palladium nanoparticles using a triphasic segmented flow in a hybrid milli–meso flow reactor, which not only allows us to completely eliminate fouling over extended operational duration, but also allows the achievement of ∼10 L per day volumetric productivity in a single-channel reactor. From the synthesis perspective, we select the harshest challenge for this demonstration – the aqueous flow synthesis of metal nanoparticles using the strong, gas-evolving reducing agent sodium borohydride. We also present comparative evaluations of the catalytic activities of flow-synthesized nanoparticles compared to their batch counterparts in a model hydrogenation reaction to highlight the consistency and quality of the nanoparticles produced by the scaled-up flow synthesis.
相关文献
Gas-phase dissociative electron attachment to flavonoids and possible similarities to their metabolic pathways
Stanislav A. Pshenichnyuk
DOI: 10.1039/C2CP43379F
Plasma electrochemistry: voltammetry in a flame plasma electrolyte
Atif Elahi, Daren J. Caruana
DOI: 10.1039/C2CP43431H
General treatment of the multimode Jahn–Teller effect: study of fullerenecations
Harry Ramanantoanina, Matija Zlatar, Pablo García-Fernández, Claude Daul
DOI: 10.1039/C2CP43591H
Naphthalene bisimides asymmetrically and symmetrically N-substituted with triarylamine – comparison of spectroscopic, electrochemical, electronic and self-assembly properties
Renata Rybakiewicz, David Djurado, Robert Nowakowski, Petr Toman, Jiri Pfleger, Jean-Marie Verilhac, Malgorzata Zagorska, Adam Pron
DOI: 10.1039/C2CP43505E
The catalytic mechanism of glyceraldehyde 3-phosphate dehydrogenase from Trypanosoma cruzi elucidated via the QM/MM approach
Cláudio Nahum Alves, Jerônimo Lameira, Iñaki Tuñón, Sergio Martí, Vicent Moliner
DOI: 10.1039/C3CP43968B
An advanced sodium-ion rechargeable battery based on a tin–carbon anode and a layered oxide framework cathode
Seung-Taek Myung, Min-Woo Jang, Jusef Hassoun
DOI: 10.1039/C3CP00070B
Towards a highly-efficient fuel-cell catalyst: optimization of Pt particle size, supports and surface-oxygen group concentration
Navaneethan Muthuswamy, Jose Luis Gomez de la Fuente, Piotr Ochal, Rajiv Giri, Steinar Raaen, Svein Sunde, Magnus Rønning, De Chen
DOI: 10.1039/C3CP43659D
Polymer-regulated epitaxial crystallization of methanofullerene on mica
Lidong Zheng, Jiangang Liu, Yanchun Han
DOI: 10.1039/C2CP42614E
A photoinduced charge transfer composite of graphene oxide and ferrocene
Subash Sharma, Koichi Wakita, Masayoshi Umeno, Yasuhiko Hayashi, Masaki Tanemura
DOI: 10.1039/C2CP43427J
您可能还喜欢
2-(甲基磺酰基)嘧啶-5-胺(CAS号:56621-92-2)适用哪些法规指南?
该化合物适用的法规指南包括GHS(全球化学品统一分类和标签制度)分类为特定目标器官毒性-单次接触类别3;根据欧盟REACH法规,该化合物需要进行注册和评估;在美...
在合成中是否有4-(4-氯苯基)-1H-咪唑(CAS号:35512-29-9)的替代品?
在合成中,可以考虑使用一些类似的化合物作为4-(4-氯苯基)-1H-咪唑的替代品,如4-(4-溴苯基)-1H-咪唑或4-(4-甲氧基苯基)-1H-咪唑。这些化合...
什么是N~2~-甲基丙氨酸酰胺(CAS号:32012-16-1)?
N~2~-甲基丙氨酸酰胺是一种有机化合物,其化学名为2-(Methylamino)propanamide。它是一种酰胺类化合物,分子式为C4H10N2O,相对分...
如何处理含有N-苄基-3-氨基氧杂环丁烷草酸盐(CAS号:1956341-96-0)的废料?
处理含有N-苄基-3-氨基氧杂环丁烷草酸盐(CAS号:1956341-96-0)的废料时,应首先确保遵循相关法规要求,如GHS和REACH等。通常,废液应先进行...
4-bromo-2-chloro-6-methylbenzoic acid(CAS号:877149-07-0)的物理化学性质是什么?
4-溴-2-氯-6-甲基苯甲酸是一种固体化合物,具有较高的熔点和较低的沸点。它的分子量为261.03 g/mol。该化合物在水中几乎不溶,在有机溶剂中溶解度适中...
2-[(2,5-二氯-4-嘧啶)氨基]-N-甲基苯甲酰胺(CAS号:761440-08-8)通常如何合成?
该化合物通常通过缩合反应合成,典型的方法是将2,5-二氯嘧啶与N-甲基苯甲酰胺在碱性条件下进行偶联反应。常用的碱包括NaH、LDA等强碱。该合成路线具有较高的选...
在合成中是否有3,5-二溴-4-甲基苯胺(CAS号:13194-73-5)的替代品?
3,5-二溴-4-甲基苯胺在某些合成路线中可能没有直接替代品。然而,在某些应用场景下,可以考虑使用其他类似结构的化合物如3,5-二溴-4-硝基苯胺或3,5-二碘...
2-氯喹啉-4-羧酸甲酯(CAS号:62482-26-2)的主要用途是什么?
2-氯喹啉-4-羧酸甲酯主要用于有机合成和药物合成领域,作为中间体或原料。它在合成某些药物和染料时具有重要作用。此外,该化合物还可能用于某些特定的化学研究中。
i>]吡啶(CAS号:474708-88-8)安全吗?
6-溴-8-氯咪唑[1,2-a]吡啶在操作过程中需要谨慎以确保安全。该化合物具有一定的毒性,吸入其蒸气或粉尘可能导致呼吸道刺激。处理时应佩戴适当的防护装备,如手...
来源期刊
Reaction Chemistry & Engineering

Reaction Chemistry & Engineering is an interdisciplinary journal reporting cutting-edge research focused on enhancing the understanding and efficiency of reactions. Reaction engineering leverages the interface where fundamental molecular chemistry meets chemical engineering and technology. Challenges in chemistry can be overcome by the application of new technologies, while engineers may find improved solutions for process development from the latest developments in reaction chemistry. Reaction Chemistry & Engineering is a unique forum for researchers whose interests span the broad areas of chemical engineering and chemical sciences to come together in solving problems of importance to wider society. All papers should be written to be approachable by readers across the engineering and chemical sciences. Papers that consider multiple scales, from the laboratory up to and including plant scale, are particularly encouraged.













![2,4,5-Trichloro-7H-pyrrolo[2,3-d]pyrimidine structure 2,4,5-Trichloro-7H-pyrrolo[2,3-d]pyrimidine structure](https://cnstatic.chemtradehub.com/structs/105/1053228-28-6-fba3.webp)
