The radical acylarylation of N-arylacrylamides with aliphatic aldehydes using the photolysis of hypervalent iodine(iii) reagents

文献信息

发布日期 2018-07-14
DOI 10.1039/C8OB01420E
影响因子 3.876
作者

Ryu Sakamoto, Naomichi Hirama


查看原文

摘要

This article describes a variety of 3,3-disubstituted 2-oxindoles that bear carbonyl groups, which are efficiently obtained from a radical reaction between N-arylacrylamides and aliphatic aldehydes. The reaction is initiated by the photolysis of hypervalent iodine(III) reagents and proceeds smoothly under mild, metal-free conditions.

相关文献

Quantifying anisotropic dielectric response properties of nanoconfined water within graphene slit pores

Sergi Ruiz-Barragan, Saskia Körning, Dominik Marx

2020-04-27 Communication

DOI: 10.1039/D0CP00916D

Introducing mesoscopic charge transfer rates into molecular electronics

Adriano Santos, Ushula M. Tefashe, Richard L. McCreery, Paulo R. Bueno

2020-04-27 Communication

DOI: 10.1039/D0CP01621G

FB-REDA: fragment-based decomposition analysis of the reorganization energy for organic semiconductors

Kun-Han Lin, Clémence Corminboeuf

2020-05-12 Paper

DOI: 10.1039/D0CP01722A

Exciton transfer free energy from Car–Parrinello molecular dynamics

Christian Schwermann, Nikos L. Doltsinis

2020-01-16 Paper

DOI: 10.1039/C9CP06419B

The unexpected effect of aqueous ion pairs on the forbidden n → π* transition in nitrate

Pernille D. Pedersen, Kurt V. Mikkelsen, Matthew S. Johnson

2020-04-28 Paper

DOI: 10.1039/D0CP00958J

Inside back cover

Cover

DOI: 10.1039/D0CP90133D

Photon-mediated charge exchange reactions between 39K atoms and 40Ca+ ions in a hybrid trap

Hui Li, S. Jyothi, Ming Li, Kenneth R Brown, Svetlana Kotochigova

2020-04-22 Paper

DOI: 10.1039/D0CP01131B

Ionization energies in solution with the QM:QM approach

Zsuzsanna Tóth, Jakub Kubečka, Eva Muchová, Petr Slavíček

2020-01-22 Paper

DOI: 10.1039/C9CP06154A

Role of image charges in ionic liquid confined between metallic interfaces

Samuel Ntim, Marialore Sulpizi

2020-03-20 Paper

DOI: 10.1039/D0CP00409J

您可能还喜欢

化合物问答

如何储存1,2-环己二酮环乙缩醛(CAS号:4746-96-7)?

1,2-环己二酮环乙缩醛应储存在阴凉、干燥、通风良好的地方,避免阳光直射。建议使用密封容器保存,并保持环境温度在室温范围内,远离火源和热源。

4746-96-71,4-Dioxaspiro[4.5]d...
化合物问答

Ecopladib(CAS号:381683-92-7)的市场或研究趋势如何?

Ecopladib作为一种新型的药物,主要应用于治疗高胆固醇等疾病。目前,市场和研究趋势显示,Ecopladib因其独特的药理作用而受到关注。随着对心血管疾病治...

381683-92-7Ecopladib
化合物问答

2,3-Dimethyl-3H-imidazo[4,5-c]pyridine(CAS号:52538-09-7)通常如何合成?

2,3-二甲基-3H-咪唑[4,5-c]吡啶通常通过咪唑和2,3-二甲基吡啶的缩合反应合成。具体来说,将咪唑和2,3-二甲基吡啶在适当的溶剂中进行加热或加压反应...

52538-09-72,3-Dimethyl-3H-imid...
化合物问答

2,3,4,5-tetrahydro-1H-3-苯并氮杂环;盐酸盐(CAS号:17379-01-0)的市场或研究趋势如何?

该化合物在药物化学和有机合成中有一定的应用。近年来,随着对新型药物化合物的需求增加,该化合物的研究趋势主要集中在探索其生物活性,尤其是其在神经系统疾病治疗中的潜...

17379-01-02,3,4,5-Tetrahydro-1...
化合物问答

解草嗪(CAS号:68-90-6)安全吗?

解草嗪具有一定的化学毒性,因此在操作过程中需要采取适当的防护措施。应避免吸入、皮肤接触和眼睛接触。处理时应佩戴化学防护手套、实验服和护目镜。

68-90-6(2-Ethyl-1-benzofura...
化合物问答

如何储存盐酸甘氨酸丁酯(CAS号:13048-99-2)?

盐酸甘氨酸丁酯应储存在阴凉、干燥、通风良好的地方,避免阳光直射和高温环境,温度应控制在25℃以下。储存容器应密封,避免与空气中的水分和酸性物质接触,以防发生水解...

13048-99-2Butyl glycinate hydr...
化合物问答

什么是2-Iodo-N,N-dimethylbenzamide(CAS号:54616-46-5)?

2-碘-N,N-二甲基苯胺是一种有机化合物,化学名为2-Iodo-N,N-dimethylbenzamide。其分子式为C<sub>9</sub>H<sub>1...

54616-46-52-Iodo-N,N-dimethylb...
化合物问答

如何储存2-氨基-N-环己基乙酰胺(CAS号:16817-90-6)?

应储存于阴凉、干燥、通风良好的地方,避免高湿度和光照,最好存放在密封容器中。

16817-90-6N-Cyclohexylglycinam...
化合物问答

5-溴-2-(4H-1,2,4-三唑-4-基)吡啶(CAS号:959240-99-4)的市场或研究趋势如何?

随着医药、农药和新材料领域的发展,该化合物作为关键中间体的应用日益增多。特别是在药物合成中,由于其独特的化学性质,可以用于合成多种药物分子。未来的研究趋势可能集...

959240-99-45-Bromo-2-(4H-1,2,4-...
化合物问答

2,4-二溴-6-三氟甲基嘧啶(CAS号:785778-00-9)通常如何合成?

2,4-二溴-6-三氟甲基嘧啶通常通过溴化反应合成。首先,将6-三氟甲基嘧啶与溴化剂(如液溴)在适当的溶剂(如二氯甲烷、四氢呋喃)中反应,加入适当的催化剂(如四...

785778-00-92,4-Dibromo-6-(trifl...

来源期刊

Organic & Biomolecular Chemistry

Organic & Biomolecular Chemistry
CiteScore: 3.4
自引率: 10.3%
年发文量: 1041

Organic & Biomolecular Chemistry (OBC) publishes original and high impact research and reviews in organic chemistry. We welcome research that shows new or significantly improved protocols or methodologies in total synthesis, synthetic methodology or physical and theoretical organic chemistry as well as research that shows a significant advance in the organic chemistry or molecular design aspects of chemical biology, catalysis, supramolecular and macromolecular chemistry, theoretical chemistry, mechanism-oriented physical organic chemistry, medicinal chemistry or natural products. Articles published in the journal should report new work which makes a highly-significant impact in the field. Routine and incremental work is generally not suitable for publication in the journal. More details about key areas of our scope are below. In all cases authors should include in their article clear rationale for why their research has been carried out.

推荐供应商

免责声明
本页面提供的学术期刊信息仅供参考和研究使用。我们与任何期刊出版商均无关联,也不处理投稿事宜。如有投稿相关咨询,请直接联系相关期刊出版商。
如发现页面信息有误,请发送邮件至 support@chemtradehub.com 联系我们。我们将及时核实并处理您的问题。