Functional polyamides with gem-diazido units: synthesis and diversification

文献信息

发布日期 2018-11-09

DOI 10.1039/C8PY01087K

影响因子 5.582

作者

Phillip Biallas, Janina Heider, Stefan F. Kirsch

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摘要

A diazidated malonate derivative was employed as a monomer for the reagent-free one-pot synthesis of several polyamides containing geminal diazido moieties within the polymer backbone. Using different diamines, azide-rich polyamides with diverse properties and sensitivities dependent on the structure of the diamine units were obtained. Postpolymerization CuAAC reactions of the geminal diazido units in the polymer backbone allowed for the introduction of additional functionalities, and the construction of densely functionalized polymeric structures.

期刊推荐

Geotextiles and Geomembranes

Composite Structures

Natural Product Reports

Journal of the Royal Society of New Zealand

Cellular Polymers

Composites Science and Technology

Applied Organometallic Chemistry

Chemical Society Reviews

Chemistry Letters

Organometallics

来源期刊

Polymer Chemistry

CiteScore: 8.6

自引率: 7.3%

年发文量: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Functional polyamides with gem-diazido units: synthesis and diversification

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来源期刊

Polymer Chemistry

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