5,10,15,20-tetrakis(4-boronic acid pinacol ester phenyl) porphyrin
CAS号:
1332748-00-1
分子式:
C68H74B4N4O8
Visible light enabled γ-trifluoromethylation of Baylis–Hillman acetates: stereoselective synthesis of trisubstituted alkenes
文献信息
发布日期
2019-02-14
DOI
10.1039/C9QO00166B
影响因子
5.281
作者
Arvind Kumar Yadav, Anup Kumar Sharma, Krishna Nand Singh
查看原文
摘要
A distinct visible light induced γ-trifluoromethylation of Baylis–Hillman acetates has been accomplished using eosin Y as a photoredox catalyst and bench stable Langlois’ reagent (CF3SO2Na) as a CF3 source under metal-free conditions at room temperature to afford various trisubstituted alkenes. The product stereochemistry is predominantly trans (E), and involves trifluoromethylation followed by de-acetoxylation.
期刊推荐
Kinetics and Catalysis
Nature
Proceedings of the National Academy of Sciences of the United States of America
Planta Medica
Journal of Physics and Chemistry of Solids
Helvetica Chimica Acta
Pharmacological Reviews
Pure and Applied Chemistry
Organic Preparations and Procedures International
Molecular Pharmacology
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来源期刊
Organic Chemistry Frontiers
CiteScore:
7.8
自引率:
8.7%
年发文量:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
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