![(2S)-2-{[(9H-Fluoren-9-ylmethoxy)carbonyl]amino}-4-(methylselanyl)butanoic acid structure](https://cnstatic.chemtradehub.com/structs/121/1217852-49-7-f252.webp "(2S)-2-{[(9H-Fluoren-9-ylmethoxy)carbonyl]amino}-4-(methylselanyl)butanoic acid structure")
Pd(ii)/Ag(i)-Cocatalyzed ortho direct arylation of O-phenylcarbamates with pinacol aryl boronates
文献信息
发布日期
2019-03-05
DOI
10.1039/C9QO00227H
影响因子
5.281
作者
Huijun Ma, Tao Wang, Chenying Gao, Guangshen Li, Minghao Zhang
查看原文
摘要
Ortho direct arylation of O-phenylcarbamates using aryl boronates as coupling partners has been realized for the first time in the literature. A mechanistic investigation showed that the Wheland intermediate with ortho C–H remaining after carbopalladation was the key intermediate for further transformation. Isotope competition experiments indicated that C–H cleavage was not involved in the rate-determining step.
期刊推荐
Journal of Asian Natural Products Research
Polycyclic Aromatic Compounds
Heteroatom Chemistry
Cellulose
Journal of Chemical Sciences
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Critical Reviews in Solid State and Materials Sciences
Acta Metallurgica Sinica-English Letters
Herald of the Russian Academy of Sciences
Bioorganic & Medicinal Chemistry
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来源期刊
Organic Chemistry Frontiers
CiteScore:
7.8
自引率:
8.7%
年发文量:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
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CAS号:
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分子式:
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