Synthetic approach to skeletally diverse nitrogen heterocycles from dicyano-2-methylenebut-3-enoates
文献信息
Wen-Lin Zou, Qing-Zhu Li, Xin Feng, Zhi-Qiang Jia, Yue Liu
The [2 + 1], formal-[4 + 1] and [5 + 1] annulations of electron-deficient dienes with ambiphilic nitrogen reagents were developed on the basis of a similar vinylogous aza-Michael addition. These synthetic approaches enable the divergent synthesis of several interesting heterocyclic skeletons, such as vinylaziridines, pyrroline and 2-aminopyridines, from easily accessible starting materials under mild conditions.
期刊推荐

Russian Journal of Coordination Chemistry

Russian Journal of Organic Chemistry

Crystallography Reports

Russian Journal of Applied Chemistry

Current Opinion in Solid State & Materials Science

Saudi Pharmaceutical Journal

Acta Materialia

Chemical Communications

Current Opinion in Colloid & Interface Science

Journal of Peptide Science
相关文献
Abnormal scaling of excitons in phosphorene quantum dots
Jun Zhong, Linan Huang, Weidong Sheng
DOI: 10.1039/C9CP06146K
Correction: Enhancement of electron accepting ability of para-benzoquinone by a single water molecule
Golda Mensa-Bonsu, Aude Lietard, Jan R. R. Verlet
DOI: 10.1039/D0CP90056G
Novel inorganic aromatic mixed-valent superalkali electride CaN3Ca: an alkaline-earth-based high-sensitivity multi-state nonlinear optical molecular switch
Yin-Feng Wang, Tian Qin, Jia-Min Tang, Yan-Jiao Liu, Miao Xie, Jia Li, Jiangen Huang, Zhi-Ru Li
DOI: 10.1039/C9CP06848A
Raman shift, Néel temperature, and optical band gap of NiO nanoparticles
Bai Pan, Xianshang Meng, Yidong Xia, Haiming Lu, Hui Li
DOI: 10.1039/C9CP06989E
Turing patterns modulation by chemical gradient in isothermal and non-isothermal conditions
Leonardo Silva-Dias, Alejandro Lopez-Castillo
DOI: 10.1039/D0CP00650E
Strain analysis from M-edge resonant inelastic X-ray scattering of nickel oxide films
P. S. Miedema, I. Alonso Calafell, C. Schüßler-Langeheine, M. Beye
DOI: 10.1039/C9CP03593A
Cation vacancy related crystal structure and bandgap and their effects on the thermoelectric performance of Cu-ternary systems Cu3+δIn5Te9 (δ = 0–0.175)
Yafen Xia, Yong Luo, Jiaolin Cui
DOI: 10.1039/D0CP00626B
Mechanistic insight into photocrosslinking reaction between triplet state 4-thiopyrimidine and thymine
Xiaoran Zou, Zhonghua Sun, Hongmei Zhao, Chun-yang Zhang
DOI: 10.1039/C9CP04089G
Zn-Doped Cu(100) facet with efficient catalytic ability for the CO2 electroreduction to ethylene
Yuefeng Zhang, Yong Zhao, Caiyun Wang, Zengxi Wei, Junliang Yang
DOI: 10.1039/C9CP03692J
Boron-based inorganic heterocyclic clusters: electronic structure, chemical bonding, aromaticity, and analogy to hydrocarbons
Lin-Yan Feng, Rui Li, Hua-Jin Zhai
DOI: 10.1039/C9CP03254A
您可能还喜欢
(3-氨苯基)环丙基甲酮(CAS号:162174-75-6)的主要用途是什么?
(3-氨苯基)环丙基甲酮主要用于合成化学中间体,特别是在药物化学领域作为原料。它还可以用于有机合成反应中,作为催化剂或反应物。
如何储存亚胺菌(CAS号:136470-79-6)?
亚胺菌应储存在干燥、阴凉处,避免直接暴露于光线下。建议使用密封容器储存,防止吸潮和污染。具体的储存条件应参考产品的安全数据表(MSDS)或药品说明书。
2-氯-2,2-二氟乙酰胺(CAS号:354-28-9)应用于哪些行业?
2-氯-2,2-二氟乙酰胺在医药、聚合物、传感器、半导体等领域有广泛应用。在医药领域,它作为中间体用于合成其他药物;在聚合物领域,用作聚合引发剂或稳定剂;在传感...
处理4-甲基-3-硝基-1,1-联苯(CAS号:53812-68-3)时应注意哪些实验室安全事项?
在处理4-甲基-3-硝基-1,1-联苯时,应佩戴手套、护目镜和实验室外套等个人防护装备(PPE),确保在通风橱中操作以减少吸入风险。若发生泄露,应立即使用沙子或...
(2S)-羟基(苯基)乙酸 (2R)-N-苄基-1-(4-甲氧基苯基)丙-2-胺盐(CAS号:188690-84-8)应用于哪些行业?
该化合物广泛应用于医药、聚合物和半导体行业。在医药领域,它是某些药物中间体的重要组成部分;在聚合物领域,可用作增塑剂;在半导体行业,可用于制造光刻胶。
在合成中是否有芬苯哒唑砜-D3标准品(CAS号:1228182-49-7)的替代品?
芬苯哒唑砜-D3标准品的替代品可能包括类似的苯并咪唑类化合物,如芬苯哒唑本身或其非同位素标记版本。这些替代品在结构上与芬苯哒唑砜-D3相似,但在具体应用中需进行...
2-氟-4-硝基苯乙酸(CAS号:315228-19-4)通常如何合成?
2-氟-4-硝基苯乙酸可以通过一系列化学反应合成,通常是从4-氟苯胺开始,首先进行硝化反应生成4-氟-2-硝基苯胺,然后进行乙酰化反应得到目标产物。具体的合成步...
2-氟-4-甲氧基苯乙酸(CAS号:883531-28-0)通常如何合成?
2-氟-4-甲氧基苯乙酸通常通过将4-甲氧基苯乙酸与氟化试剂(如氟化氰)反应来合成。反应通常在无水条件下进行,使用催化剂如六氟磷酸锂或四氟硼酸锂以提高选择性和产...
什么是4SC 202;4SC202(CAS号:1186222-89-8)?
4SC 202;4SC202是一种化学化合物,其化学名称为(2E)-N-(2-氨基苯基)-3-(1-{[4-(1-甲基-1H-吡唑-4-基)苯基]磺酰基}-1H...
来源期刊
Organic Chemistry Frontiers

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry




