Facile synthesis of a porous polynorbornene with an azobenzene subunit: selective adsorption of 4-nitrophenol over 4-aminophenol in water

文献信息

发布日期 2020-09-28

DOI 10.1039/D0PY00994F

影响因子 5.582

作者

Shan-Qing Peng, Butian Zhang, Wenhao Fan, Shuifeng Wang, Zhi-Hao Zhang, Yan Liu, Shi-Lu Chen, Mu-Hua Huang

查看原文

摘要

This paper reports the design and facile synthesis of porous polynorbornenes containing a 4,4′-dialkoxy-azobenzene subunit (named Azo-POP-13 and Azo-POP-14). They were synthesized by the robust reductive azo-coupling polymerization of the Ring-Opening-Metathesis-Polymerization (ROMP) product on bis-para-nitrophenylether of the norbornene diol. The polymerization rate of exo-NBNPE (kapp = 18.7 × 10−2 s−1) is faster than that of endo-NBNPE (kapp = 3.64 × 10−2 s−1). The as-synthesized Azo-POP-13 was found to selectively adsorb 4-nitrophenol (4-NP) over 4-aminophenol (4-AP) in water, with a selectivity up to 14.6 and good recyclability.

期刊推荐

Electroanalysis

Chinese Journal of Chemistry

Atomization and Sprays

NDT & E International

Polycyclic Aromatic Compounds

Journal of the Indian Institute of Science

Main Group Chemistry

Cellulose

Medicinal Chemistry Research

Bioorganic & Medicinal Chemistry Letters

来源期刊

Polymer Chemistry

CiteScore: 8.6

自引率: 7.3%

年发文量: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Facile synthesis of a porous polynorbornene with an azobenzene subunit: selective adsorption of 4-nitrophenol over 4-aminophenol in water

文献信息

期刊推荐

相关文献

Immobilization of individual cells by local photo-polymerization on a chip

Rapid, quantitative analysis of ppm/ppb nicotine using surface-enhanced Raman scattering from polymer-encapsulated Ag nanoparticles (gel-colls)

New chemical evidence for the ability to generate radical molecular ions of polyenes from ESI and HR-MALDI mass spectrometry

Encapsulation of multi-walled carbon nanotubes (MWCNTs) in Ba2+-alginate to form coated micro-beads and their application to the pre-concentration/elimination of dibenzo-p-dioxin, dibenzofuran, and biphenyl from contaminated water

Human-centric intelligent systems for exploration and knowledge discovery

A SIFT-MS study of positive and negative ion chemistry of the ortho-, meta- and para-isomers of cymene, cresol, and ethylphenol

Enhancing the ionic conductivity and mechanical properties of PEO-based solid electrolytes through thermal pre-stretching treatment

Comparison of diffuse-reflectance absorbance and attenuated total reflectance FT-IR for the discrimination of bacteria

Thermal stability of azole-rich energetic compounds: their structure, density, enthalpy of formation and energetic properties

SELEX: Just another separation?

您可能还喜欢

硅烷偶联剂ZQ-172(CAS号：1067-53-4)的主要用途是什么？

如何处理含有6-(2,4-二甲氧基苯基)-2-吡啶甲醇(CAS号：887981-31-9)的废料？

甲砜霉素甘氨酸酯盐酸盐(CAS号：2611-61-2)的物理化学性质是什么？

如何储存反式-环丙烷-1,2-二胺双盐酸盐(CAS号：3187-76-6)？

什么是吩嗪硫酸甲酯(CAS号：299-11-6)？

N1-异丙基二乙烯三胺(CAS号：207399-20-0)的市场或研究趋势如何？

4,4-Dimethyl-5,6-dihydro-4H-cyclopenta[d][1,3]thiazol-2-amine(CAS号：1182284-47-4)应用于哪些行业？

处理5-(PYRIDIN-4-YL)-OXAZOL-2-YLAMINE(CAS号：1014629-83-4)时应注意哪些实验室安全事项？

什么是伊托必利N-氧化物(CAS号：141996-98-7)？

氟氯烟酸(CAS号：82671-06-5)安全吗？

来源期刊

Polymer Chemistry

推荐化合物

4-Chloro-2,3-dimethylpyridine 1-oxide

6-Chloro-3-pyridinol

Platinum(2+) dichloride

Ethyl N-benzylglycinate

EthylenediaminetetraaceticacidcalciumDisodiumsalthydrate

推荐供应商