Copolymerisation of 1-alkenes with bulky oxygen-containing olefins for dual-stage functionalisation of polyolefins

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发布日期 2020-11-18

DOI 10.1039/D0PY01303J

影响因子 5.582

作者

Makoto Nakamura, Kohtaro Osakada

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摘要

Pd–Diimine complexes catalyse the copolymerisation of 1-alkenes with olefins having a bulky oxygen-containing substituent, either 4-methyl-1-vinyl-2,6,7-trioxabicyclo[2.2.2]octane (VTO) or 2-methyl-2-vinyl-1,3-dioxolane (MVD), to afford a copolymer containing functional groups (up to 34 mol% of the total repeating units). The repeating units from VTO and MVD are mainly incorporated into the terminal of the branches and the main chain of the copolymer, respectively. Hydrolysis of the resulting copolymers by CF3COOH affords polymers with COOH or COMe substituents, which are difficult to obtain efficiently by the direct copolymerisation of acrylic acid or methyl vinyl ketone.

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来源期刊

Polymer Chemistry

CiteScore: 8.6

自引率: 7.3%

年发文量: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Copolymerisation of 1-alkenes with bulky oxygen-containing olefins for dual-stage functionalisation of polyolefins

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Contents

Ion-interaction chromatography of zwitterions. The fractional charge approach to model the influence of the mobile phase concentration of the ion-interaction reagent

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来源期刊

Polymer Chemistry

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