Ligand-controlled copper-catalyzed 1,2 or 1,4-protoborylation of 2-trifluoromethyl-1,3-conjugated enynes

文献信息

发布日期 2020-05-13
DOI 10.1039/D0QO00445F
影响因子 5.281
作者

Jialu Li, Chuan Liu, Jingjing He, Sixue Xu, Xianghu Zhao, Yue Zhu, Song Cao


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摘要

A novel ligand-controlled highly regioselective synthesis of CF3-substituted homopropargylboronates and homoallenylboronates via copper-catalyzed 1,2 or 1,4-protoborylation of 2-trifluoromethyl-1,3-conjugated enynes with B2pin2 was developed.

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Organic Chemistry Frontiers

Organic Chemistry Frontiers
CiteScore: 7.8
自引率: 8.7%
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Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

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