Metal-free chemoselective hydrogenation of unsaturated carbon–carbon bonds via cathodic reduction
文献信息
发布日期
2020-06-04
DOI
10.1039/D0QO00547A
影响因子
5.281
作者
Yongwei Qin, Jingjun Lu, Zirong Zou, Huanliang Hong, Yamei Li, Yibiao Li, Lu Chen, Jinhui Hu, Yubing Huang
查看原文
摘要
A straightforward protocol for efficient and highly selective hydrogenation of unsaturated carbon–carbon bonds via electrochemical reduction has been reported. A series of chain alkanes and carbonyl compounds are produced under metal-free and external-reductant-free electrolytic conditions. Scale-up experiments have exhibited the potential applications of this protocol in practical synthesis. Deuterium-labelling experiments demonstrate that both DMSO and H2O in the reaction system can provide hydrogen atoms for the reaction.
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来源期刊
Organic Chemistry Frontiers
CiteScore:
7.8
自引率:
8.7%
年发文量:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
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