![N-[(9Z)-9-Octadecen-1-yl]-1,3-propanediamine structure](https://cnstatic.chemtradehub.com/structs/717/7173-62-8-d43e.webp "N-[(9Z)-9-Octadecen-1-yl]-1,3-propanediamine structure")
Engineering oxygen vacancies on dendrite-like IrO2 for the oxygen evolution reaction in acidic solution
文献信息
发布日期
2020-02-27
DOI
10.1039/D0SE00007H
影响因子
6.367
作者
Chao Cai, Shaobo Han, Yongliang Tang
查看原文
摘要
Here we report IrO2 with dendrite-like nanostructures (DLNs) as a catalyst for the oxygen evolution reaction (OER) in acidic solution. The IrO2 DLNs are prepared by the molten salt method and have self-standing three dimensional structures. IrO2 with DLNs has a high mass activity determined to be 19-fold that of commercial IrO2. Combining a wide array of ex situ characterization methods, we demonstrate that the sublayer Ir cations and lattice O participate in the OER. The Ir corrosion and O/OH− adsorption during the OER can lead to IrO2 surface reconstruction, from a compressed one to a stretched one.
期刊推荐
Journal of the Indian Institute of Science
Medicinal Chemistry Research
Main Group Chemistry
NDT & E International
Bioorganic & Medicinal Chemistry Letters
Herald of the Russian Academy of Sciences
Colloid Journal
Journal of Chemical Sciences
Biocatalysis and Biotransformation
Acta Metallurgica Sinica-English Letters
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