Recent advances in catalytic enantioselective direct C–H bond functionalization of electron-deficient N-containing heteroarenes

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发布日期 2021-09-22

DOI 10.1039/D1QO01223A

影响因子 5.281

作者

Xiao-Lan Liu, Luo-Bin Jiang, Mu-Peng Luo, Zhi Ren, Shou-Guo Wang

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摘要

Catalytic enantioselective direct C–H bond functionalization of electron-deficient N-containing heteroarenes represents one of the most straightforward and powerful protocols to construct diverse enantioenriched highly functionalized N-heteroarene products. Efficient catalytic systems and a variety of strategies for highly chemo- and stereoselective C–H functionalization of electron-deficient N-containing heteroarenes have been developed over the past few decades. This review summarized the rapid progress in the catalytic asymmetric C–H functionalization of N-containing heteroarenes and discussed the challenges and potential of the field in the current stage.

期刊推荐

Electroanalysis

Journal of Asian Natural Products Research

Acta Metallurgica Sinica-English Letters

Critical Reviews in Solid State and Materials Sciences

Bioorganic & Medicinal Chemistry

Medicinal Chemistry Research

NDT & E International

Main Group Chemistry

Journal of the Indian Institute of Science

Biocatalysis and Biotransformation

来源期刊

Organic Chemistry Frontiers

CiteScore: 7.8

自引率: 8.7%

年发文量: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Recent advances in catalytic enantioselective direct C–H bond functionalization of electron-deficient N-containing heteroarenes

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Facile synthesis of the daphnane and tigliane framework by semi-flow tube-based-bubbling photooxidation and diastereoselective conjugate addition

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The protecting group enabled para-selective C–H benzylation of anilides via iron(ii) catalysis: a convenient approach for the synthesis of triarylmethanes

Cocatalyst-controlled divergent cascade cycloaddition reaction of arylalkynols and dioxopyrrolidienes: access to spiroketals and oxa-bridged eight-membered cyclic ethers

Aromatization-driven deconstruction/refunctionalization of unstrained rings

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