The protecting group enabled para-selective C–H benzylation of anilides via iron(ii) catalysis: a convenient approach for the synthesis of triarylmethanes
文献信息
发布日期
2020-06-10
DOI
10.1039/D0QO00402B
影响因子
5.281
作者
Yi Han, Guobao Li, Lingling Liu, Chenyang Dai, Da-Qing Shi, Yingsheng Zhao
查看原文
摘要
We report the para-selective C–H benzylation of phenyl carbamate with an iron(II) catalyst. This new method provides an efficient and convenient approach for the synthesis of triarylmethanes starting from readily available anilines and diphenylmethane. Preliminary mechanistic studies revealed that the iron(II) catalyst was essential and the use of the sterically demanding isobutoxy group led to high para-selectivity.
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来源期刊
Organic Chemistry Frontiers
CiteScore:
7.8
自引率:
8.7%
年发文量:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
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