N-doped engineering of a high-voltage LiNi0.5Mn1.5O4 cathode with superior cycling capability for wide temperature lithium–ion batteries
文献信息
Mingzhu Li, Qingping Li, Maofeng Hu, Yongxu Du, Zhipeng Duan, Hongguang Fan, Yongpeng Cui, Shuang Liu, Yongcheng Jin, Wei Liu
Spinel LiNi0.5Mn1.5O4 (LNMO) is one potential cathode candidate for next-generation high energy-density lithium–ion batteries (LIBs). However, serious capacity decay from its poor structural stability, especially at high operating temperatures, shadows its application prospects. In this work, N-doped LNMO (LNMON) was synthesized by a facile co-precipitation method and multistep calcination, exhibiting a unique yolk–shell architecture. Concurrently, N dopants are introduced into a LNMO lattice, endowing LNMON with a more stable structure via stronger Ni–N/Mn–N bindings. Benefiting from the synergistic effect of the yolk–shell structure and N-doped engineering, the obtained LNMON cathode exhibits an impressive rate and the state-of-the-art cycling capability, delivering a high capacity of 103 mA h g−1 at 25 °C after 8000 cycles. Even at a high operating temperature of 60 °C, the capacity retention remains at 92% after 1000 cycles. The discovery of N dopants in improving the cycling capability of LNMO in our case offers a prospective approach to enable 5 V LNMO cathode materials with excellent cycling capability.
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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.












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