Anion-encapsulating, discrete prism and extended frusta, from trimetallated triangular macrocycles and linkers
文献信息
Hai-Ping Wang, Zhi-Gang Gu, Nathalie Gruber
Reaction of a trinuclear triangular macrocyclic complex Pb3L(CF3SO3)6 with bidentate linkers in a ratio of 3 equiv. of linker per 2 equiv. of complex, produces a prismatic structure with 4,4′-dipyridyl, and two unprecedented, extended 3D frustum-like structures with 1,2-di(4-pyridyl)ethylene and 1,4-di(4-pyridyl)benzene. The cavities of these structures encapsulate triflate anions.
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Chemical Communications

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