D–A–D–T-type four-component radical dual-difunctionalization and acylative azidation of two different alkenes
文献信息
Ren-Xiang Liu, Xin Chen, Luo Yang
From a single alkene to two different alkenes! An iron-catalyzed four-component reaction involving an aldehyde, two different alkenes and TMSN3 is developed to assemble these four reactants in an orderly fashion based on the inherent nucleophilic/electrophilic reaction activity of the radicals and alkenes via a double radical addition, providing various multifunctional compounds containing an azido group and two carbonyl groups.
相关文献
Theoretical investigation of the solid–liquid phase transition in protonated water clusters
Kseniia Korchagina, Aude Simon, Mathias Rapacioli, Fernand Spiegelman, Jean-Marc L’Hermite, Isabelle Braud, Sébastien Zamith, Jérôme Cuny
DOI: 10.1039/C7CP04863G
Towards a taxonomy of topology for polynuclear aromatic hydrocarbons: linking electronic and molecular structure
Erin M. Adkins, J. Houston Miller
DOI: 10.1039/C7CP06048C
Dynamic encapsulation of corannulene molecules into a single-walled carbon nanotube
Y. Joko, R. Sasaki, K. Shintani
DOI: 10.1039/C7CP05542K
Unravelling redox processes of Li7MnN4 upon electrochemical Li extraction–insertion using operando XAS
D. Muller-Bouvet, N. Emery, N. Tassali, E. Panabière, C. Cénac-Morthe, A. Michalowicz, J. P. Pereira-Ramos
DOI: 10.1039/C7CP05207C
Catalytic CVD synthesis of boron nitride and carbon nanomaterials – synergies between experiment and theory
Ben McLean, Clothilde A. Eveleens, Izaac Mitchell, Grant B. Webber, Alister J. Page
DOI: 10.1039/C7CP03835F
Reply to the ‘Comment on “Elucidation of charge-transfer SERS selection rules by considering the excited state properties and the role of electrode potential”’ by M. Mohammadpour, M. H. Khodabandeh, L. Visscher and Z. Jamshidi, Phys. Chem. Chem. Phys., 2017, 19, 7833
Zahra Jamshidi, Mohammad Hassan Khodabandeh, Mozhdeh Mohammadpour, Lucas Visscher
DOI: 10.1039/C7CP05175A
In situ observation of Pt oxides on the low index planes of Pt using surface enhanced Raman spectroscopy
Fumiya Sugimura, Nanami Sakai, Tetsuya Nakamura, Masashi Nakamura, Katsuyoshi Ikeda, Toshio Sakai, Nagahiro Hoshi
DOI: 10.1039/C7CP04277A
Planarization of B20 clusters by Si and C atom substitution
Qi Liang Lu, Qi Quan Luo, Yi De Li, Shou Guo Huang
DOI: 10.1039/C7CP05610A
Excited-states of a rhenium carbonyl diimine complex: solvation models, spin–orbit coupling, and vibrational sampling effects
Sebastian Mai, Maria Fumanal, Aurora Muñoz-Losa, Chantal Daniel, Leticia González
DOI: 10.1039/C7CP05126C
Monitoring thermally induced structural deformation and framework decomposition of ZIF-8 through in situ temperature dependent measurements
Ben Xu, Yingjie Mei, Zhenyu Xiao, Zixi Kang, Rongming Wang, Daofeng Sun
DOI: 10.1039/C7CP04694D
您可能还喜欢
如何处理含有8-氯咪唑并[1,2-A]吡嗪(CAS号:69214-33-1)的废料?
处理含有8-氯咪唑并[1,2-A]吡嗪的废料时,应首先将其收集并进行化学回收或降解。如果无法回收,需采用安全的化学处理方法,如中和、氧化还原或沉淀。处理过程中需...
Calhex 231 hydrochloride(CAS号:2387505-78-2)适用哪些法规指南?
Calhex 231 hydrochloride 需要遵循《全球化学品统一分类和标签制度》(GHS)的分类和标签要求,以及欧盟的《化学品注册、评估、授权和限制条...
11-Beta,17-alpha,21-三羟基-5-beta-孕烯-3,20-二酮(CAS号:1482-50-4)的物理化学性质是什么?
11-Beta,17-alpha,21-三羟基-5-beta-孕烯-3,20-二酮是一种无色结晶性粉末,分子量为372.45 g/mol。该化合物在水中的溶解度...
处理5-异丙基-1,3,4-恶二唑-2-羧酸(CAS号:944907-13-5)时应注意哪些实验室安全事项?
处理5-异丙基-1,3,4-恶二唑-2-羧酸时应注意以下安全事项:穿戴适当的个人防护装备,包括实验室外套、手套和护目镜;操作应在通风橱中进行,以减少吸入或接触有...
benzyl 3-bromopropanoate(CAS号:90841-55-7)安全吗?
Benzyl 3-bromopropanoate属于有毒物质,吸入、摄入或皮肤接触均可能对人体造成伤害。操作时应佩戴防护眼镜、口罩和手套,避免吸入蒸汽和直接接触...
什么是(R)-N-苄氧羰基-3,4-二氢-1H-异喹啉羧酸(CAS号:151004-88-5)?
(R)-N-苄氧羰基-3,4-二氢-1H-异喹啉羧酸是一种含有苄氧羰基和异喹啉环结构的化合物,分子式为C17H15NO3。它是一种有机化合物,具有一定的生物活性...
在合成中是否有1-苄基吡啶嗡-3-羧酸盐(CAS号:15990-43-9)的替代品?
可以考虑使用1-苄基吡啶-3-羧酸盐作为1-苄基吡啶嗡-3-羧酸盐的替代品。此外,还可以探索其他类似物,如1-苄基吡啶-3-氨基甲酸酯等。具体的替代品选择需根据...
(2,6-二甲基吡啶-3-基)甲醇(CAS号:582303-10-4)安全吗?
(2,6-二甲基吡啶-3-基)甲醇在使用时需注意安全,应避免吸入其蒸汽,接触皮肤和眼睛。操作应在通风良好的环境中进行,佩戴适当的个人防护装备。
5-溴-2-乙烯基吡啶(CAS号:226883-52-9)的物理化学性质是什么?
5-溴-2-乙烯基吡啶是一种有机化合物,外观为白色固体,具有良好的结晶性。分子量约为190.03 g/mol。它的溶解性在水中较差,但在有机溶剂如二氯甲烷、甲醇...
2-羟基-3-硝基-5-甲基吡啶(CAS号:7464-14-4)应用于哪些行业?
2-羟基-3-硝基-5-甲基吡啶主要应用于医药、聚合物和半导体行业。在医药领域,它可以用作合成其他药物的中间体。在聚合物领域,它可以作为功能性单体参与聚合反应,...
来源期刊
Chemical Communications

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry














