An environment friendly electrochemical synthesis of 1,1,4,4-tetramethyl-2-tetrazene energetic materials from undimethylhydrazine
文献信息
发布日期
2023-11-07
DOI
10.1039/D3CC04693A
影响因子
6.222
作者
Qi Xue, Mi Zhang, Liang He, Fu-Qing Bi, Bo-Zhou Wang, Bin Liu
查看原文
摘要
As a prospective alternative liquid propellant, 1,4,4-tetramethyl-2-tetrazene (TMTZ) possesses high enthalpy of formation and environment friendly decomposition products, and shows a promising application prospect in aerospace, munitions manufacturing, etc. An environment friendly and convenient synthesis of TMTZ through electrochemical oxidative coupling of undimethylhydrazine (UDMH) on commercially procured electrodes was carried out under mild conditions, in which the purity is up to 98.5% with a yield of over 45%. It is a simple, clean and suitable method for industrial production in contrast with the previously reported conventional chemical oxidation syntheses.
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来源期刊
Chemical Communications
CiteScore:
8.6
自引率:
4.7%
年发文量:
2458
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