Rapid classification of heavy metal soils from different mining areas by using a GSCV quadratic merit seeking network combined with MF-LIBS

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发布日期 2023-09-22
DOI 10.1039/D3JA00254C
影响因子 4.023
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摘要

Focusing on the problems of complicated sample processing and long detection time of traditional soil composition testing in mining areas, this paper proposes a rapid soil classification method of grid search and cross validation (GSCV) quadratic optimization-seeking network combined with magnetic field enhanced laser-induced breakdown spectroscopy (MF-LIBS), which can quickly and accurately classify standard soil samples from 10 different mining areas. First, the effects of different magnetic field strengths on the enhancement factor, signal-to-noise ratio (SNR) and plasma electron temperature of the characteristic spectral lines were investigated. Next, 5400 12 248-dimensional spectral data under the 0.98 T magnetic field constraint were preprocessed using principal component analysis (PCA). Then the back propagation (BP) network was optimized by combining the sparrow search algorithm (SSA) external optimization network with the genetic algorithm (GA) internal optimization network. Finally, the hyperparameters of the optimal network architecture are refined by GSCV for secondary optimization. By comparing with the unoptimized network, the results show that the classification accuracy of GSCV-SSA-GA-BP is 0.99997, the precision is 0.99977, the recall is 0.99981, and the F1-score is 0.99979. The proposed technique of GSCV quadratic optimization network combined with MF-LIBS soil classification can not only play an important role in soil research, but also provide a new scheme for rapid detection and high-precision qualitative analysis of soil components.

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来源期刊

Journal of Analytical Atomic Spectrometry

Journal of Analytical Atomic Spectrometry
CiteScore: 6.2
自引率: 25.8%
年发文量: 254

The Journal of Analytical Atomic Spectrometry (JAAS) is the central journal for publishing innovative research on fundamentals, instrumentation, and methods in the determination, speciation and isotopic analysis of (trace) elements within all fields of application. This includes, but is not restricted to, the most recent progress, developments and achievements in all forms of atomic and elemental detection, isotope ratio determination, molecular analysis, plasma-based analysis and X-ray techniques. The journal welcomes full papers, communications, technical notes, critical and tutorial review articles, editorials, and comments, in addition to the Atomic Spectrometry Updates (ASU) literature reviews that are prepared by an expert panel. Submissions are welcome in the following areas, but note this list reflects the current scope and authors are strongly encouraged to contact the Editorial team if they believe that their work offers potentially new and emerging research relevant to the journal remit: Fundamental studies in the following. New and existing sources for atomic emission, absorption, fluorescence and mass spectrometry and those that provide both atomic and molecular information Sample introduction techniques for solids, liquids, gases Improvements in sensitivity, selectivity, precision, accuracy and/or robustness Isotope ratio measurements, including techniques for improving precision and mass bias correction Single channel and multichannel simultaneous detection systems Chemometrics, statistics, calibration techniques and internal standardisation Theoretical and numerical modelling of fundamental processes related to all of the above methodologies Novel or improved methodologies in areas of application including, but not limited to the following. Biosciences, including elemental, speciation and isotopic analysis in biological systems, immunoassays based on metal-labeled antibodies, bio-imaging, and nanoparticle toxicology Geochemistry Environmental science Materials science, including engineered nanoparticles and quantum dots Metrology, including reference materials Forensic analysis Food and agricultural sciences Energy Archaeometry Molecular analysis. Molecular sources for elemental and isotopic analysis Atomic sources for molecular analysis Atomic and molecular techniques simultaneously used for complementary chemical information All contributions are judged on originality and quality of scientific content, and appropriateness of length to content of new science.

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