Hydrothermal conversion of cerium oxalate to CeO2: a parade of oxalate and water coordination modes

文献信息

发布日期 2023-12-11

DOI 10.1039/D3NJ04635D

影响因子 3.591

作者

Navid Assi, Christophe Lahoud, Petr Brázda, Dominika Zákutná, Daniel N. Rainer, Jakub Hraníček, Jan Rohlíček, Václav Tyrpekl

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摘要

Hydrothemal conversion of lanthanide/actinide oxalate salts to nanocrystalline oxide has gained technological importance in the chemistry of f-elements. Herein, we present a study describing the mechanism behind the hydrothermal recrystallization and decomposition of cerium (and Ce-Gd) oxalate to oxide. Structural determination of all intermediate nanocrystalline products was possible thanks to three-dimensional electron diffraction. This work reveals the enormous structural abilities of simple oxalate ligands.

期刊推荐

Composites Science and Technology

Journal of the Royal Society of New Zealand

Experimental Techniques

Cellular Polymers

Chemical Society Reviews

Ceramics International

Fire Safety Journal

Fire and Materials

Organometallics

Natural Product Reports

来源期刊

New Journal of Chemistry

CiteScore: 5.3

自引率: 3.7%

年发文量: 2153

NJC (New Journal of Chemistry) is a broad-based primary journal encompassing all branches of chemistry and its sub-disciplines. It contains full research articles, communications, perspectives and focus articles. This well-established journal, owned by the Centre National de la Recherche Scientifique (CNRS) of France, has been co-published with the Royal Society of Chemistry since January 1998. NJC is the forum for the publication of high-quality, original and significant work that opens new directions in chemistry or other scientific disciplines. In addition to having a significant chemical component, work published in NJC must demonstrate that it will have an impact on areas of research other than that of the reported work.

Hydrothermal conversion of cerium oxalate to CeO2: a parade of oxalate and water coordination modes

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来源期刊

New Journal of Chemistry

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