Orthogonal polymerization of aziridine with cyclic carbonates for constructing amphiphilic block copolymers

文献信息

发布日期 2023-10-31

DOI 10.1039/D3PY01045G

影响因子 5.582

作者

Xiao-Hui Guo, Ge-Ge Gu, Tian-Jun Yue, Wei-Min Ren

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摘要

Herein, we describe a novel strategy for synthesizing amphiphilic block copolymers, comprising acidified polyamine and polycarbonate segments, by the orthogonal polymerization of aziridine and cyclic carbonates. Controlled experiments revealed that the cationic ring-opening polymerization (ROP) of aziridine and the anionic ROP of cyclic carbonates proceeded simultaneously to accomplish chain propagation.

期刊推荐

Journal of Catalysis

Helvetica Chimica Acta

Science

Russian Chemical Reviews

Pure and Applied Chemistry

Organic Preparations and Procedures International

Proceedings of the National Academy of Sciences of the United States of America

Journal of Organometallic Chemistry

Journal of Physics and Chemistry of Solids

Journal of Heterocyclic Chemistry

来源期刊

Polymer Chemistry

CiteScore: 8.6

自引率: 7.3%

年发文量: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Orthogonal polymerization of aziridine with cyclic carbonates for constructing amphiphilic block copolymers

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来源期刊

Polymer Chemistry

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