Transformations of carbohydrate derivatives enabled by photocatalysis and visible light photochemistry
文献信息
发布日期
2024-01-02
DOI
10.1039/D3SC05400D
影响因子
9.825
作者
Daniel J. Gorelik, Shrey P. Desai, Sofia Jdanova, Julia A. Turner, Mark S. Taylor
查看原文
摘要
This review article highlights the diverse ways in which recent developments in the areas of photocatalysis and visible light photochemistry are impacting synthetic carbohydrate chemistry. The major topics covered are photocatalytic glycosylations, generation of radicals at the anomeric position, transformations involving radical formation at non-anomeric positions, additions to glycals, processes initiated by photocatalytic hydrogen atom transfer from sugars, and functional group interconversions at OH and SH groups. Factors influencing stereo- and site-selectivity in these processes, along with mechanistic aspects, are discussed.
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来源期刊
Chemical Science
CiteScore:
14.4
自引率:
3.9%
年发文量:
1413
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