Aqueous solutions at pressures up to 2 GPa: gas–gas equilibria, closed loops, high-pressure immiscibility, salt effects and related phenomena
文献信息
It is the aim of the present article to review the immiscibility phenomena found in our experiments on aqueous solutions of organic substances up to 2 GPa. The pressure dependence of liquid–liquid phase equilibria of systems exhibiting upper and lower critical solution temperatures, the complicated phase behavior of closed loop systems under pressure and the influence of a third substance (mixed solvent, mixed solute, added salt) on mutual miscibility are considered. The thermodynamic conditions that hold for the critical phenomena found are summarized. The interference with gas–liquid critical phenomena is also briefly discussed from a phase-theoretical point of view, including the exhibition of gas–gas equilibria.
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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.










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