Preferential solvation in mixed solvents. Part 11. Eight additional completely miscible aqueous co-solvent binary mixtures and the relationship between the volume-corrected preferential solvation parameters and the structures of the co-solvents
文献信息
The Kirkwood–Buff integrals and the volume-corrected preferential solvation parameters for the first solvation shell of the completely miscible aqueous binary mixtures of 1,3-oxolane, γ-butyrolactone, diethylamine, 1,2-diaminoethane, pyrrolidine, morpholine, N-methylacetamide and N,N,N′,N′-tetramethylurea were calculated from thermodynamic data at the temperatures for which these data were available. The preferential solvation parameters of these and 33 additional mixtures for which they have been published are related to the structures of the co-solvents.
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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.













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