Enantioselective allylation of aldehydes catalyzed by chiral indium(iii) complexes immobilized in ionic liquids

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发布日期 2005-03-15

DOI 10.1039/B500086F

影响因子 6.222

作者

Shun-Jun Ji

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摘要

In the presence of chiral catalytic complexes prepared from In(OTf)3 and chiral PYBOX ligands, allytributylstannane reacted with aldehydes in ionic liquids to afford the corresponding homoallylic alcohols in high enantioselectivities (86–94% ee) and good yields (68–89%); the chiral catalysts immobilized in ionic liquids could be reused with comparable enantioselectivities and yields.

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来源期刊

Chemical Communications

CiteScore: 8.6

自引率: 4.7%

年发文量: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Enantioselective allylation of aldehydes catalyzed by chiral indium(iii) complexes immobilized in ionic liquids

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