An azido–metal–isonicotinate complex showing long-range ordered ferromagnetic interaction: synthesis, structure and magnetic properties
文献信息
Yong-Fei Zeng, Fu-Chen Liu, Jiong-Peng Zhao, Shuang Cai, Xian-He Bu, Joan Ribas
A new 3D CuII complex [Cu1.5(N3)2(isonicotinate)]n [1], which features two types of bridging modes for azide (μ1,1 and the rare asymmetric μ1,1,3) where the three bonds of the μ1,1,3-N3− group to Cu exhibit three different distances, has been synthesized and characterized, and magnetic measurements indicate that [1] experiences long-range ferromagnetic ordering at approximately 6 K.
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Chemical Communications

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry














