The P(bth)2− anion as a Janus head staple between lithium and manganese (bth = benzothiazol-2-yl, C7H4NS)
文献信息
Thomas Stey, Julian Henn, Dietmar Stalke
Deprotonation of HP(bth)2 (1) affords the lithium phosphanide [(Et2O)2Li(bth)2P], (2) with both nitrogen atoms coordinated to the lithium atom while in the heterobimetallic complex [Li(bth)2P{Mn(CO)2Cp}2]n (3) additionally the phosphorus atom μ-bridges two Mn(CO)2Cp residues.
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Chemical Communications

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