Lewis acidity enhancement of organoboranes viaoxidation of appended ferrocene moieties

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发布日期 2007-05-01

DOI 10.1039/B701807J

影响因子 6.222

作者

Krishnan Venkatasubbaiah, Israel Nowik, Rolfe H. Herber, Frieder Jäkle

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摘要

The Lewis acidity of boron in diboradiferrocene 1 is strongly enhanced through oxidation of the iron atoms as evident from examination of X-ray structural parameters of the mixed-valent cation 1+PF6 and further confirmed from the strong complexation of MeCN to the dication in 22+(I3)2.

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来源期刊

Chemical Communications

CiteScore: 8.6

自引率: 4.7%

年发文量: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Lewis acidity enhancement of organoboranes viaoxidation of appended ferrocene moieties

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