Heterogeneous electron transfer at Au/SAM junctions in a room-temperature ionic liquid under pressure

文献信息

发布日期 2008-02-25
DOI 10.1039/B719787J
影响因子 6.222
作者

Peter Illner, Rudi van Eldik


查看原文

摘要

Proven electrochemical approaches were applied to study heterogeneous electron transfer (ET) between selected redox couples and gold electrodes modified with alkanethiol self-assembled monolayers (SAMs), using the room-temperature ionic liquid (RTIL) [bmim][NTf2] as reaction medium; ferrocene as freely diffusing redox probe in the RTIL was tested for ET through both thin (butanethiol) and thick (dodecanethiol) assemblages at pressures up to 150 MPa; well behaved kinetic patterns and reproducibility of data were demonstrated for ET within the unique Au/SAM/RTIL arrays.

相关文献

A chemist’s approach to biochemical complexity

2003-01-27 Focus

DOI: 10.1039/B211529H

A distance-controlled oligopeptide linker as a novel photo-induced energy transfer switch by secondary structural transition

Akira Kishimoto, Toshiki Mutai, Koji Araki

2003-02-25 Communication

DOI: 10.1039/B212851A

A unique eclipsed 2-D coordination polymer with removable iodine molecules in the open-channel structure

Jack Y. Lu, Amy M. Babb

2003-05-13 Communication

DOI: 10.1039/B210740F

Amplified quenching in metal–organic conjugated polymers

Yao Liu, Shujun Jiang, Kirk S. Schanze

2003-02-10 Communication

DOI: 10.1039/B211575A

Chiral shape and enantioselective growth of colloidal particles of self-assembled meso-tetra(phenyl and 4-sulfonatophenyl)porphyrins

Joaquim Crusats, Josep Claret, Ismael Díez-Pérez, Zoubir El-Hachemi, Héctor García-Ortega, Raimon Rubires, Francesc Sagués, Josep M. Ribó

2003-05-29 Communication

DOI: 10.1039/B303273F

Determination of binding affinities on solid supports: influence of the loading and the nature of the solid support

Matteo Conza, Helma Wennemers

2003-02-28 Communication

DOI: 10.1039/B212703B

Stabilisation of an ortho-deprotonated mesityl group within the unusual [{2,4,6-Me3C6H2P}{4,6-Me2C6H2(2-CH2)P}Sn]3− stannate ion

Mary McPartlin, Anthony D. Woods, Christopher M. Pask, Thomas Vogler, Dominic S. Wright

2003-05-21 Communication

DOI: 10.1039/B303390M

Activator-free oxidative homocoupling of organosilanes catalysed by a palladium–DPPP complex

Hiroto Yoshida, Yasuhito Yamaryo, Joji Ohshita, Atsutaka Kunai

2003-05-21 Communication

DOI: 10.1039/B303852A

Synthesis and characteristion of LixBC—hole doping does not induce superconductivity

A. M. Fogg, J. B. Claridge, G. R. Darling, M. J. Rosseinsky

2003-05-19 Communication

DOI: 10.1039/B302058D

Bifunctional receptor triad for efficient recognition of mono- and dicarboxylic acids

Karol Kacprzak, Jacek Gawronski

2003-06-03 Communication

DOI: 10.1039/B302003G

您可能还喜欢

化合物问答

2-Bromo-4-chloro-1-(difluoromethyl)benzene(CAS号:1261476-50-9)的市场或研究趋势如何?

随着环保要求的提高和安全意识的增强,该化合物的研究和应用趋势正逐渐转向更安全、更环境友好的替代品。市场关注点主要集中在开发新型合成方法和绿色化学路径,以减少有害...

1261476-50-92-Bromo-4-chloro-1-(...
化合物问答

如何处理含有2,9 - 二苯基-1,10 - 菲罗啉(CAS号:25677-69-4)的废料?

处理含有2,9 - 二苯基 - 1,10 - 菲罗啉的废料时,应先将其收集在适当的容器中,避免与其他化学品混合。随后,可以通过水解或氧化等方法进行处理,直至达到...

25677-69-42,9-Diphenyl-1,10-ph...
化合物问答

处理(6-氯-吡嗪-3-基)-(4-乙基-哌嗪-1-基)-甲酮(CAS号:1178836-15-1)时应注意哪些实验室安全事项?

处理(6-氯-吡嗪-3-基)-(4-乙基-哌嗪-1-基)-甲酮时,应穿戴适当的个人防护装备(PPE),包括手套、护目镜和实验室外套。在通风橱中操作以确保良好的通...

1178836-15-1(6-Chloro-3-pyridazi...
化合物问答

处理(R)-2-氯-1-(2,4-二氯苯基)乙醇(CAS号:114446-57-0)时应注意哪些实验室安全事项?

在处理(R)-2-氯-1-(2,4-二氯苯基)乙醇时,应佩戴防护眼镜、实验室外套和手套,确保通风橱开启以减少接触和吸入的风险。避免直接接触皮肤和眼睛。处理过程中...

114446-57-0(1R)-2-Chloro-1-(2,4...
化合物问答

在合成中是否有3-氯-6-(3-氯哌啶-1-基)吡嗪(CAS号:1185310-37-5)的替代品?

可考虑使用类似结构的化合物作为替代品,如3-氯-6-(哌啶-1-基)吡嗪或3-氯-6-(2-氯哌啶-1-基)吡嗪,这些化合物在结构上与目标化合物相似,可能具有相...

1185310-37-53-Chloro-6-(3-chloro...
化合物问答

苯并三氮唑-5-甲酸乙酯(CAS号:73605-91-1)通常如何合成?

该化合物可以通过乙酸乙酯与5-溴-1H-苯并三氮唑的反应合成,通常在无水条件下进行。合成过程中,需要使用适当的溶剂如乙酸乙酯,并在适当的温度下反应。该反应具有较...

73605-91-1Ethyl 1H-benzotriazo...
化合物问答

什么是一水硫酸镁(CAS号:14168-73-1)?

一水硫酸镁是一种无机化合物,化学式为MgSO₄·H₂O,CAS号为14168-73-1。它由镁离子、硫酸根离子和一个结晶水分子组成,通常呈现为白色粉末或颗粒状固...

14168-73-1Magnesium sulfate hy...
化合物问答

氘代-1,3-二氯-2-丙醇(CAS号:1173020-20-6)应用于哪些行业?

氘代-1,3-二氯-2-丙醇主要应用于医药和有机合成领域,作为研究化合物的氘代替代品,用于标记和追踪反应过程。此外,在聚合物和半导体生产中也有一定的应用潜力。

1173020-20-61,3-Dichloro-2-(~2~H...
化合物问答

如何储存氰乙酸环己酯(CAS号:52688-11-6)?

氰乙酸环己酯应储存在阴凉、干燥、通风良好的环境中,远离火源和热源,防止阳光直射。储存容器应密封良好,避免与空气接触,防止发生不必要的反应。

52688-11-6Cyclohexyl cyanoacet...
化合物问答

2-碘-4-硝基苯胺(CAS号:6293-83-0)的市场或研究趋势如何?

目前,2-碘-4-硝基苯胺在医药和农药领域有一定的研究和应用,尤其是在开发新型药物和农药产品方面。然而,由于其潜在的环境和健康风险,行业正趋向于寻找更为安全和环...

6293-83-02-iodo-4-nitroanilin...

来源期刊

Chemical Communications

Chemical Communications
CiteScore: 8.6
自引率: 4.7%
年发文量: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

推荐供应商

免责声明
本页面提供的学术期刊信息仅供参考和研究使用。我们与任何期刊出版商均无关联,也不处理投稿事宜。如有投稿相关咨询,请直接联系相关期刊出版商。
如发现页面信息有误,请发送邮件至 support@chemtradehub.com 联系我们。我们将及时核实并处理您的问题。