Trapped-molecule charge-transfer complexes with huge dipoles: M–C2F6–X (M = Na to Cs, X = Cl to I)

文献信息

发布日期 2008-10-17
DOI 10.1039/B807614F
影响因子 3.676
作者

Fedor Y. Naumkin


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摘要

Novel intermolecular complexes, with a small molecule sterically trapped between a pair of ions, are designed and characterized. The molecule is found to undergo minor shape distortions and to remain almost neutral, and the complexes to have very large dipole moments (up to ∼40 D). The systems’ stability, ion-molecule interaction and stored energy are investigated, and the vertical excitation, ionization and electron-attachment are described. Variations of geometry and of the above properties with the alkali-metal and halogen components are analysed as well.

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来源期刊

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
自引率: 10.3%
年发文量: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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