Advances in CO2 activation by frustrated Lewis pairs: from stoichiometric to catalytic reactions

文献信息

发布日期 2023-11-09

DOI 10.1039/D3SC03907B

影响因子 9.825

作者

Yara van Ingen, Tribani Boruah, Adam McLauchlan, Thomas Wirth, Rebecca L. Melen

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摘要

The rise of CO2 concentrations in the environment due to anthropogenic activities results in global warming and threatens the future of humanity and biodiversity. To address excessive CO2 emissions and its effects on climate change, efforts towards CO2 capture and conversion into value adduct products such as methane, methanol, acetic acid, and carbonates have grown. Frustrated Lewis pairs (FLPs) can activate small molecules, including CO2 and convert it into value added products. This review covers recent progress and mechanistic insights into intra- and inter-molecular FLPs comprised of varying Lewis acids and bases (from groups 13, 14, 15 of the periodic table as well as transition metals) that activate CO2 in stoichiometric and catalytic fashion towards reduced products.

期刊推荐

Current Topics in Medicinal Chemistry

Phytochemistry Reviews

Annual Review of Materials Research

Organic & Biomolecular Chemistry

Catalysis Communications

Letters in Organic Chemistry

Nature Methods

Nature Materials

Mini-Reviews in Organic Chemistry

Dalton Transactions

来源期刊

Chemical Science

CiteScore: 14.4

自引率: 3.9%

年发文量: 1413

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Advances in CO2 activation by frustrated Lewis pairs: from stoichiometric to catalytic reactions

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来源期刊

Chemical Science

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