B–H Activation by frustrated Lewis pairs: borenium or boryl phosphonium cation?

文献信息

发布日期 2008-07-16

DOI 10.1039/B808348G

影响因子 6.222

作者

Meghan A. Dureen, A. Lough, Thomas M. Gilbert, Douglas W. Stephan

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摘要

Catechol borane reacts with the frustrated Lewis pairs tBu2RP (R = tBu, 2-C6H4(C6H5)) and B(C6F5)3 to give the species [(C6H4O2)BPtBu2R][HB(C6F5)3] that can formally be described as either borenium cation or boryl-phosphonium salts; the nature of these species was probed with DFT calculations.

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来源期刊

Chemical Communications

CiteScore: 8.6

自引率: 4.7%

年发文量: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

B–H Activation by frustrated Lewis pairs: borenium or boryl phosphonium cation?

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来源期刊

Chemical Communications

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