Unusual temperature dependence of salt effects for “on water” Wittig reaction: hydrophobicity at the interface

文献信息

发布日期 2008-07-28

DOI 10.1039/B809127G

影响因子 6.222

作者

Shraeddha Tiwari, Anil Kumar

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摘要

An unusual variation with temperature of the salt effects in aqueous Wittig reaction is observed, suggesting that hydrophobic acceleration of reactions comprising “on water” reactants is fundamentally different from that for reactions with small non-polar solutes.

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来源期刊

Chemical Communications

CiteScore: 8.6

自引率: 4.7%

年发文量: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Unusual temperature dependence of salt effects for “on water” Wittig reaction: hydrophobicity at the interface

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