The effects of hydrogen bonds on metal-mediated O2activation and related processes
文献信息
发布日期
2008-10-01
DOI
10.1039/B810957E
影响因子
6.222
作者
Ryan L. Shook, A. S. Borovik
查看原文
摘要
Hydrogen bonds stabilize and direct chemistry performed by metalloenzymes. With inspiration from enzymes, we will utilize an approach that incorporates intramolecular hydrogen bond donors to determine their effects on the stability and reactivity of metal complexes. Our premise is that control of secondary coordination sphere interactions will promote new function in synthetic metal complexes. Multidentate ligands have been developed that create rigid organic structures around metal ions. These ligands place hydrogen bond (H-bond) donors proximal to the metal centers, forming specific microenvironments. One distinguishing attribute of these systems is that site-specific modulations in structure can be readily accomplished, in order to evaluate correlations with reactivity. A focus of this research is consideration of dioxygen binding and activation by metal complexes, including developing structure–function relationships in metal-assisted oxidative catalysis.
相关文献
3,5-Bis(trifluoromethyl)benzyl modified triazine-based covalent organic frameworks suppressing the shuttle effect of polysulfides in lithium-sulfur batteries
Shirui Pang, Yuxin Liu, Zhe Zhang, Yuxin Li, Chunguang Li, Zhan Shi, Shouhua Feng
2023-11-23
Communication
DOI: 10.1039/D3NJ03791F
Optimization of iron oxide nanoparticles for MRI-guided magnetic hyperthermia tumor therapy: reassessing the role of shape in their magnetocaloric effect
Francisco Gámez, Roberto Gallardo, Manuel Pernia Leal
2023-11-03
Paper
DOI: 10.1039/D3TB01821K
An aptamer-assisted nanopore strategy with a salt gradient for direct protein sensing
Peng Tang, Liang Wang, Wanyi Xie, Xiaohan Chen, Yunjiao Wang, Ting Weng, Rong Tian, Shuo Zhou, Zuobin Wang
2023-11-01
Paper
DOI: 10.1039/D3TB01875J
Injectable spontaneously formed asymmetric adhesive hydrogel with controllable removal for wound healing
Lei Liang, Xi Li, Zhouying Tan, Min Liu, Yuwei Qiu, Qingyu Yu, Chaojie Yu, Mengmeng Yao, Bingyan Guo, Pengcheng Che, Hong Zhang
2023-10-26
Paper
DOI: 10.1039/D3TB02014B
Metal–organic gels: recent advances in their classification, characterization, and application in the pharmaceutical field
Wei Cao, Zezhi Lin, Daoyi Zheng, Jianjun Zhang, Weili Heng, Yuanfeng Wei, Yuan Gao, Shuai Qian
2023-10-20
Review Article
DOI: 10.1039/D3TB01612A
3D-printing of attapulgite monoliths with superior low-temperature selective catalytic reduction activity: the influence of thermal treatment
Jiangtao Yu, Linhua Zhu, Xiaoxiao Yu, Jixing Liu, Jingzhou Yin, Peiwen Wu, Jian Liu
2023-12-07
Paper
DOI: 10.1039/D3NJ04023B
A specific amino-based fluorescent probe for mercury ion detection in water samples, cells, and zebrafish
Miaohui Yu, Tingting Fu, Wenzhai Li, Yan Zhang, Huayan Wen, Min Zheng, Moran Shi, Caiyun Liu, Meng Jin, Kechun Liu, Baocun Zhu
2023-11-23
Paper
DOI: 10.1039/D3NJ04746F
Development of novel microsphere structured – calcium tungstate as efficacious electrocatalyst for the detection of antibiotic drug nitrofurantoin
P. Manikanta, Mounesh, Rohit Rangnath Nikam, S. Sandeep, Bhari Mallanna Nagaraja
2023-11-20
Paper
DOI: 10.1039/D3TB02087H
Chitosan functionalized gold nanostars as a theranostic platform for intracellular microRNA detection and photothermal therapy
Xiaoxue Dong, Zongwei Zhu, Qian Sun, Hongqian Zhang, Chuanxu Yang
2023-11-02
Paper
DOI: 10.1039/D3TB02029K
Influence of neutral auxiliary ligands on crystal structure and magnetic behaviour of new [Mn II2Mn III2] clusters supported by p-adamantylcalix[4]arene
Alexander S. Ovsyannikov, Aida I. Samigullina, Daut R. Islamov, Mikhail A. Cherosov, Ruslan G. Batulin, Airat G. Kiiamov, Aidar T. Gubaidullin, Pavel V. Dorovatovskii, Svetlana E. Solovieva, Igor S. Antipin
2023-11-20
Paper
DOI: 10.1039/D3NJ04809H
您可能还喜欢
化合物问答
(3-氨苯基)环丙基甲酮(CAS号：162174-75-6)的主要用途是什么？
(3-氨苯基)环丙基甲酮主要用于合成化学中间体，特别是在药物化学领域作为原料。它还可以用于有机合成反应中，作为催化剂或反应物。
162174-75-6(3-Aminophenyl)(cycl...
化合物问答
如何储存亚胺菌(CAS号：136470-79-6)？
亚胺菌应储存在干燥、阴凉处，避免直接暴露于光线下。建议使用密封容器储存，防止吸潮和污染。具体的储存条件应参考产品的安全数据表（MSDS）或药品说明书。
136470-79-6Abacavir EP Impurity...
化合物问答
2-氯-2,2-二氟乙酰胺(CAS号：354-28-9)应用于哪些行业？
2-氯-2,2-二氟乙酰胺在医药、聚合物、传感器、半导体等领域有广泛应用。在医药领域，它作为中间体用于合成其他药物；在聚合物领域，用作聚合引发剂或稳定剂；在传感...
354-28-92-Chloro-2,2-difluor...
化合物问答
处理4-甲基-3-硝基-1,1-联苯(CAS号：53812-68-3)时应注意哪些实验室安全事项？
在处理4-甲基-3-硝基-1,1-联苯时，应佩戴手套、护目镜和实验室外套等个人防护装备（PPE），确保在通风橱中操作以减少吸入风险。若发生泄露，应立即使用沙子或...
53812-68-34'-Methyl-3-nitro-1,...
化合物问答
(2S)-羟基(苯基)乙酸 (2R)-N-苄基-1-(4-甲氧基苯基)丙-2-胺盐(CAS号：188690-84-8)应用于哪些行业？
该化合物广泛应用于医药、聚合物和半导体行业。在医药领域，它是某些药物中间体的重要组成部分；在聚合物领域，可用作增塑剂；在半导体行业，可用于制造光刻胶。
188690-84-8Benzeneacetic acid, ...
化合物问答
在合成中是否有芬苯哒唑砜-D3标准品(CAS号：1228182-49-7)的替代品？
芬苯哒唑砜-D3标准品的替代品可能包括类似的苯并咪唑类化合物，如芬苯哒唑本身或其非同位素标记版本。这些替代品在结构上与芬苯哒唑砜-D3相似，但在具体应用中需进行...
1228182-49-7(~2~H_3_)Methyl [5-(...
化合物问答
2-氟-4-硝基苯乙酸(CAS号：315228-19-4)通常如何合成？
2-氟-4-硝基苯乙酸可以通过一系列化学反应合成，通常是从4-氟苯胺开始，首先进行硝化反应生成4-氟-2-硝基苯胺，然后进行乙酰化反应得到目标产物。具体的合成步...
315228-19-42-(2-fluoro-4-nitrop...
化合物问答
2-氟-4-甲氧基苯乙酸(CAS号：883531-28-0)通常如何合成？
2-氟-4-甲氧基苯乙酸通常通过将4-甲氧基苯乙酸与氟化试剂（如氟化氰）反应来合成。反应通常在无水条件下进行，使用催化剂如六氟磷酸锂或四氟硼酸锂以提高选择性和产...
883531-28-02-Fluoro-4-methoxyph...
化合物问答
什么是4SC 202;4SC202(CAS号：1186222-89-8)？
4SC 202;4SC202是一种化学化合物，其化学名称为(2E)-N-(2-氨基苯基)-3-(1-{[4-(1-甲基-1H-吡唑-4-基)苯基]磺酰基}-1H...
1186222-89-8(2E)-N-(2-Aminopheny...
132980-99-53,5-Difluorobenzamid...
来源期刊
Chemical Communications
CiteScore:
8.6
自引率:
4.7%
年发文量:
2458
ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry
推荐化合物
![[1-(5-Methyl-2-pyridinyl)-1H-pyrazol-4-yl]methanol structure](https://cnstatic.chemtradehub.com/structs/143/1439822-99-7-6cc9.webp "[1-(5-Methyl-2-pyridinyl)-1H-pyrazol-4-yl]methanol structure")
推荐供应商
免责声明
本页面提供的学术期刊信息仅供参考和研究使用。我们与任何期刊出版商均无关联，也不处理投稿事宜。如有投稿相关咨询，请直接联系相关期刊出版商。
如发现页面信息有误，请发送邮件至 support@chemtradehub.com 联系我们。我们将及时核实并处理您的问题。