Supported vanadium oxide in heterogeneous catalysis: elucidating the structure–activity relationship with spectroscopy
文献信息
Ilke Muylaert, Pascal Van Der Voort
In order to design the next generation of catalysts, it is crucial that the insights of researchers in heterogeneous catalysis, materials design and spectroscopy are merged. Since the scientific community started to realize that the molecular pattern of a catalyst at room temperature and in vacuum does by no means reflect the actual structure of the catalytic species under working conditions, new spectroscopic techniques have been developed to study the catalytic species “while doing the job” or in Latin, “operando”. In this contribution, we give an overview of recent developments in—at first sight—the simple case of supported VOx species. In the last few years, many issues on the nature of the active sites in supported VOx species have been questioned again, and the observations and conclusions summarized in this paper present a clear case of the importance of structure–activity relationships in rational catalyst design.
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来源期刊
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.














