Thermodynamics of nano- and macrocrystalline anatase using cell voltage measurements
文献信息
Palani Balaya, Joachim Maier
In view of increasing scientific and technological interest in nanomaterials, it is important to examine whether or, more exactly, to what extent the thermodynamic parameters change with size. Electrochemical e.m.f. measurements which provide a direct and elegant access to these thermodynamic data have been used in this study to investigate the excess contributions of anatase due to nano-size. The e.m.f. measurements are carried out (250–450 °C) on different particle sizes (1.2 μm–5 nm) using the cell: Au, O2, Na2Ti6O13, TiO2 (anatase) |Na-β′′ alumina |TiO2 (rutile), Na2Ti6O13, O2, Au. The e.m.f. observed is closely related to the difference of the Gibbs energies of formation (ΔfG°) of the titania crystals on both sides. Such cell voltage measurements with various sizes of anatase (1200, 100, 15, and 5 nm) as working electrodes enable us to calculate the excess enthalpy and entropy due to surface contributions and to provide refined data for the macroscopic anatase. No electrochemical Ostwald ripening or chemical Ostwald ripening was observed in the case of anatase nanoparticles up to 500 °C.
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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.














