Sustained self-organizing pH patterns in hydrogen peroxide driven aqueous redox systems
文献信息
István Szalai, Nándor Takács, Patrick De Kepper
Many pattern developments in nature are believed to result from the interplay between self-activated (bio)chemical processes and the diffusive transport of constituents. Though the details are difficult to work out, the relevance of reaction–diffusion processes is widely accepted in many aspects of biological development. Due to their easier manipulation and control, aqueous phase chemical reactions are commonly preferred to probe the patterning capacity of reaction–diffusion processes. Nonetheless, sustained patterns of such a type were observed only in reactions involving oxyhalogen compounds. We report on halogen free solution chemistry systems which lead to stationary or oscillatory spatiotemporal pH patterns. They are based on the acid autocatalytic oxidation of sulfite ions by hydrogen peroxide in combination with two significantly different proton consuming feedback reactions. Besides the chemical novelty, yet experimentally and even theoretically undocumented pattern dynamics are uncovered. This success, based on a well-defined method, further paves the way to the discovery of stationary patterns in delicate biochemical reactions.
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来源期刊
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.










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