Recent advances in the chemistry of Group 4 metal complexes incorporating [OSSO]-type bis(phenolato) ligands as post-metallocene catalysts
文献信息
Norio Nakata, Tomoyuki Toda, Akihiko Ishii
Several recent efforts concerning post-metallocene Group 4 metal complexes incorporating mixed donor [OSSO]-type tetradentate bis(phenolato) ligands are reviewed. These [OSSO]-type ligands can be mainly classified as 5–5–5, 5–6–5 and 6–5–6 arrays of chelate rings toward central metals. As the main topics are described the design and unique coordination chemistry of the [OSSO]-type ligands and catalytic activities of the resultant titanium, zirconium, and hafnium complexes as single-site catalysts for polymerizations and copolymerizations of olefins.
期刊推荐

Drug Discovery Today

Current Opinion in Colloid & Interface Science

Current Opinion in Solid State & Materials Science

Russian Journal of Organic Chemistry

New Journal of Chemistry

Chemistry Education Research and Practice

Saudi Pharmaceutical Journal

Crystallography Reports

Chemical Communications

Journal of Saudi Chemical Society
相关文献
Synthesis of thermo-responsive glycopolymersviacopper catalysed azide–alkyne ‘click’ chemistry for inhibition of ricin: the effect of spacer between polymer backbone and galactose
Gaojian Chen, Martina H. Stenzel
DOI: 10.1039/C1PY00048A
Enhancing the rigidity of a network polymer of intrinsic microporosity by the combined use of phthalocyanine and triptycene components,‡
Mohammed Hashem, C. Grazia Bezzu, Benson M. Kariuki, Neil B. McKeown
DOI: 10.1039/C1PY00288K
Poly(norbornene) block copolymer-based shell cross-linked micelles with Co(iii)–salen cores
Yu Liu, Victor Piñón, III, Marcus Weck
DOI: 10.1039/C1PY00151E
Tuning the lower critical solution temperature of thermoresponsive polymers by biospecific recognition
Jens Buller, André Laschewsky, Jean-François Lutz, Erik Wischerhoff
DOI: 10.1039/C1PY00001B
Peptide-based lipid mimetics with tunable core properties viathiol–alkyne chemistry
Jacob G. Ray, Jack T. Ly, Daniel A. Savin
DOI: 10.1039/C1PY00003A
Single site metallorganic polymerization catalysis as a method to probe the properties of polyolefins
Claudio De Rosa, Finizia Auriemma
DOI: 10.1039/C1PY00129A
您可能还喜欢
2-(甲基磺酰基)嘧啶-5-胺(CAS号:56621-92-2)适用哪些法规指南?
该化合物适用的法规指南包括GHS(全球化学品统一分类和标签制度)分类为特定目标器官毒性-单次接触类别3;根据欧盟REACH法规,该化合物需要进行注册和评估;在美...
在合成中是否有4-(4-氯苯基)-1H-咪唑(CAS号:35512-29-9)的替代品?
在合成中,可以考虑使用一些类似的化合物作为4-(4-氯苯基)-1H-咪唑的替代品,如4-(4-溴苯基)-1H-咪唑或4-(4-甲氧基苯基)-1H-咪唑。这些化合...
什么是N~2~-甲基丙氨酸酰胺(CAS号:32012-16-1)?
N~2~-甲基丙氨酸酰胺是一种有机化合物,其化学名为2-(Methylamino)propanamide。它是一种酰胺类化合物,分子式为C4H10N2O,相对分...
如何处理含有N-苄基-3-氨基氧杂环丁烷草酸盐(CAS号:1956341-96-0)的废料?
处理含有N-苄基-3-氨基氧杂环丁烷草酸盐(CAS号:1956341-96-0)的废料时,应首先确保遵循相关法规要求,如GHS和REACH等。通常,废液应先进行...
4-bromo-2-chloro-6-methylbenzoic acid(CAS号:877149-07-0)的物理化学性质是什么?
4-溴-2-氯-6-甲基苯甲酸是一种固体化合物,具有较高的熔点和较低的沸点。它的分子量为261.03 g/mol。该化合物在水中几乎不溶,在有机溶剂中溶解度适中...
2-[(2,5-二氯-4-嘧啶)氨基]-N-甲基苯甲酰胺(CAS号:761440-08-8)通常如何合成?
该化合物通常通过缩合反应合成,典型的方法是将2,5-二氯嘧啶与N-甲基苯甲酰胺在碱性条件下进行偶联反应。常用的碱包括NaH、LDA等强碱。该合成路线具有较高的选...
在合成中是否有3,5-二溴-4-甲基苯胺(CAS号:13194-73-5)的替代品?
3,5-二溴-4-甲基苯胺在某些合成路线中可能没有直接替代品。然而,在某些应用场景下,可以考虑使用其他类似结构的化合物如3,5-二溴-4-硝基苯胺或3,5-二碘...
2-氯喹啉-4-羧酸甲酯(CAS号:62482-26-2)的主要用途是什么?
2-氯喹啉-4-羧酸甲酯主要用于有机合成和药物合成领域,作为中间体或原料。它在合成某些药物和染料时具有重要作用。此外,该化合物还可能用于某些特定的化学研究中。
i>]吡啶(CAS号:474708-88-8)安全吗?
6-溴-8-氯咪唑[1,2-a]吡啶在操作过程中需要谨慎以确保安全。该化合物具有一定的毒性,吸入其蒸气或粉尘可能导致呼吸道刺激。处理时应佩戴适当的防护装备,如手...
来源期刊
Polymer Chemistry

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
![2-[({[(2-Methyl-2-propanyl)oxy]carbonyl}amino)methyl]isonicotinic acid structure 2-[({[(2-Methyl-2-propanyl)oxy]carbonyl}amino)methyl]isonicotinic acid structure](https://cnstatic.chemtradehub.com/structs/473/473924-63-9-973b.webp)



