Activators generated by electron transfer for atom transfer radical polymerization: recent advances in catalyst and polymer chemistry

文献信息

发布日期 2012-06-22

DOI 10.1039/C2PY20286G

影响因子 5.582

作者

Liangjiu Bai, Lifen Zhang, Zhenping Cheng, Xiulin Zhu

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摘要

Activators generated by electron transfer for atom transfer radical polymerization (AGET ATRP) was introduced by Matyjaszewski and coworkers in 2005. The development of AGET ATRP has profound industrial implications because it lowers the amount of necessary catalyst, while still allowing excellent control over molecular weight and molecular weight distribution. Herein, we highlight recent works on the mechanistic understanding of AGET ATRP towards the advance of catalysis and the design and synthesis of functional polymers, with a particular emphasis on: (a) mechanistic understanding of AGET ATRP; (b) reduction of catalyst concentration; (c) aqueous-phase systems by AGET ATRP; (d) iron-mediated AGET ATRP; and (e) functionnal polymers designed by AGET ATRP. AGET ATRP is a robust tool due to its simplicity, broad applicability, and its ability to prepare previously inaccessible well-defined polymeric materials.

期刊推荐

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Acta Materialia

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来源期刊

Polymer Chemistry

CiteScore: 8.6

自引率: 7.3%

年发文量: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Activators generated by electron transfer for atom transfer radical polymerization: recent advances in catalyst and polymer chemistry

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