Syntheses, crystal structures of a series of novel alkali metal or alkaline earth metal phosphites
文献信息
Jian-Han Zhang, Jun-Ling Song, Fang Kong, Jiang-Gao Mao
A series of new alkali metal and alkali-earth metal phosphites, namely, NaIn3(HPO3)5(H2O)4, AIn(HPO3)2 (A = Rb, Cs) and Ba3M2(HPO3)6 (M = Al, Ga, In), have been synthesized by hydrothermal reactions. Their structures have been determined by single-crystal X-ray diffraction. The structure of NaIn3(HPO3)5(H2O)4 shows a complicated 3D anionic framework based on InO6 octahedra connected by HPO3 tetrahedra via corner-sharing, and the 3D anionic network of NaIn3(HPO3)5(H2O)4 can also be described as a new 3,5-net with a Schläfli symbol of {4.82}{42.6.87}{42.6}3{42.88}{43.62.85}{83}. Both AIn(HPO3)2 (A = Rb, Cs) feature a 2D layer composed by InO6 octahedral and HPO3 tetrahedral units with alkali metal cations filling the interlayer spaces. Ba3M2(HPO3)6 (M = Al, Ga, In) are isomorphous, and their structures feature a 3D anionic framework composed of MO6 (M = Al, Ga, In) octahedra and HPO3 tetrahedra interconnected via corner-sharing. IR and UV-vis spectra and TGA curves of these materials were also measured.
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CrystEngComm

CrystEngComm is the forum for the design and understanding of crystalline materials. We welcome studies on the investigation of molecular behaviour within crystals, control of nucleation and crystal growth, engineering of crystal structures, and construction of crystalline materials with tuneable properties and functions. We publish hypothesis-driven research into… how crystal design affects thermodynamics, phase transitional behaviours, polymorphism, morphology control, solid state reactivity (crystal-crystal solution-crystal, and gas-crystal reactions), optoelectronics, ferroelectric materials, non-linear optics, molecular and bulk magnetism, conductivity and quantum computing, catalysis, absorption and desorption, and mechanical properties. Using Techniques and methods including… Single crystal and powder X-ray, electron, and neutron diffraction, solid-state spectroscopy, spectrometry, and microscopy, modelling and data mining, and empirical, semi-empirical and ab-initio theoretical evaluations. On crystalline and solid-state materials. We particularly welcome work on MOFs, coordination polymers, nanocrystals, host-guest and multi-component molecular materials. We also accept work on peptides and liquid crystals. All papers should involve the use or development of a design or optimisation strategy. Routine structural reports or crystal morphology descriptions, even when combined with an analysis of properties or potential applications, are generally considered to be outside the scope of the journal and are unlikely to be accepted.












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