A polyoxometalate-based polymer electrolyte with an improved electrode interface and ion conductivity for high-safety all-solid-state batteries
文献信息
Xiangfei Yuan, Cui Sun, Jia-Ning Duan, Jingmin Fan, Ruming Yuan, Jiajia Chen, Jeng-Kuei Chang, Mingsen Zheng, Quanfeng Dong
Solid electrolytes have been considered as some of the most promising candidates for next generation lithium-based batteries because they eliminate the potential safety hazards of liquid organic electrolytes and further increase the energy density of batteries. However, inherent defects such as low conductivity and poor interface compatibility with electrodes critically hinder their extensive application. Polyoxometalate Li7[V15O36(CO3)] (LVC) can dissociate Li+ in electrolyte and possesses a high diffusion coefficient, which constitute a pathway for Li+ transmission. Herein, a polyoxometalate-based polymer electrolyte (PPE) with an improved electrode interface and ion conductivity for high-safety all-solid-state batteries has been designed and synthesized to further enhance their electrochemistry behaviour. Compared with the routine PEO18LiTFSI electrolyte, the ionic conductivity was enhanced. Meanwhile, LVC can improve the interface compatibility between the electrode and electrolyte significantly, which promotes reaction kinetics and suppresses lithium dendrites against Li metal. When employed in LiFePO4|Li batteries, the specific discharge capacity after 180 cycles reached 148 mA h g−1 with a high coulombic efficiency of around 99.9% at 0.5C. According to the result of ARC, LiFePO4|C batteries with PPEs are endowed with superior safety as the onset temperature of the self-heating process reaches up to 181.4 °C and the thermal runaway process does not occur within the range of 360 °C, indicating the potential of the PPE for high-safety all-solid-state batteries.
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Journal of Materials Chemistry A

Journal of Materials Chemistry A, B & C cover high quality studies across all fields of materials chemistry. The journals focus on those theoretical or experimental studies that report new understanding, applications, properties and synthesis of materials. The journals have a strong history of publishing quality reports of interest to interdisciplinary communities and providing an efficient and rigorous service through peer review and publication. The journals are led by an international team of Editors-in-Chief and Associate Editors who are all active researchers in their fields. Journal of Materials Chemistry A, B & C are separated by the intended application of the material studied. Broadly, applications in energy and sustainability are of interest to Journal of Materials Chemistry A, applications in biology and medicine are of interest to Journal of Materials Chemistry B, and applications in optical, magnetic and electronic devices are of interest to Journal of Materials Chemistry C. More than one Journal of Materials Chemistry journal may be suitable for certain fields and researchers are encouraged to submit their paper to the journal that they feel best fits for their particular article. Example topic areas within the scope of Journal of Materials Chemistry A are listed below. This list is neither exhaustive nor exclusive. Artificial photosynthesis Batteries Carbon dioxide conversion Catalysis Fuel cells Gas capture/separation/storage Green/sustainable materials Hydrogen generation Hydrogen storage Photocatalysis Photovoltaics Self-cleaning materials Self-healing materials Sensors Supercapacitors Thermoelectrics Water splitting Water treatment










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