Chemical conversion of biomass-derived hexose sugars to levulinic acid over sulfonic acid-functionalized graphene oxide catalysts

文献信息

发布日期 2013-08-29
DOI 10.1039/C3GC40353J
影响因子 10.182
作者

Ji-Woong Yoon, Dong Won Hwang, Harold H. Kung


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摘要

Heterogeneous graphene oxide (GO)-based catalysts with sulfonic acid (SO3H) functional groups (GO–SO3H) were used for the selective decomposition of the hexose sugars, glucose and fructose into levulinic acid (LA), which has been used as a platform chemical for various value-added derivatives. The GO–SO3H catalysts gave high yields of around 78% for LA and showed good reuse compatibility with reliable performance. The chemical transformation patterns for hexose sugar decompositions are affected by the temperature, the density of acid sites, and the type of catalyst. The high catalytic performance of GO–SO3H was shown to result from the higher density of Brønsted acid sites in the GO, compared with the Lewis acid sites in other AC–SO3H catalysts. The morphology, surface characteristics, and other physiochemical properties were evaluated using several characterization techniques.

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Green Chemistry

Green Chemistry
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Green Chemistry provides a unique forum for the publication of innovative research on the development of alternative green and sustainable technologies. The scope of Green Chemistry is based on, but not limited to, the definition proposed by Anastas and Warner (Green Chemistry: Theory and Practice, P T Anastas and J C Warner, Oxford University Press, Oxford, 1998). Green chemistry is the utilisation of a set of principles that reduces or eliminates the use or generation of hazardous substances in the design, manufacture and application of chemical products. Green Chemistry is at the frontiers of this continuously-evolving interdisciplinary science and publishes research that attempts to reduce the environmental impact of the chemical enterprise by developing a technology base that is inherently non-toxic to living things and the environment. Submissions on all aspects of research relating to the endeavour are welcome. The journal publishes original and significant cutting-edge research that is likely to be of wide general appeal. To be published, work must present a significant advance in green chemistry. Papers must contain a comparison with existing methods and demonstrate advantages over those methods before publication can be considered. For more information please see this Editorial. Coverage includes the following, but is not limited to: Design (e.g. biomimicry, design for degradation/recycling/reduced toxicity…) Reagents & Feedstocks (e.g. renewables, CO2, solvents, auxiliary agents, waste utilization…) Synthesis (e.g. organic, inorganic, synthetic biology…) Catalysis (e.g. homogeneous, heterogeneous, enzyme, whole cell…) Process (e.g. process design, intensification, separations, recycling, efficiency…) Energy (e.g. renewable energy, fuels, photovoltaics, fuel cells, energy storage, energy carriers…) Applications (e.g. electronics, dyes, consumer products, coatings, pharmaceuticals, preservatives, building materials, chemicals for industry/agriculture/mining…) Impact (e.g. safety, metrics, LCA, sustainability, (eco)toxicology…) Green chemistry is, by definition, a continuously-evolving frontier. Therefore, the inclusion of a particular material or technology does not, of itself, guarantee that a paper is suitable for the journal. To be suitable, the novel advance should have the potential for reduced environmental impact relative to the state of the art. Green Chemistry does not normally deal with research associated with 'end-of-pipe' or remediation issues.

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