Retracted Article: One-pot synthesis of glycidol from glycerol and dimethyl carbonate over a highly efficient and easily available solid catalyst NaAlO2
文献信息
Rongxian Bai, Hongkun Zhang, Fuming Mei, Shu Wang, Tao Li, Guangxing Li
The one-pot synthesis of glycidol from glycerol and dimethyl carbonate (DMC) was developed by using a solid base catalyst. A series of solid base catalysts have been investigated in this reaction. It was found that NaAlO2, a cheap and easily available raw material, was a highly efficient heterogeneous catalyst for the one-pot synthesis of glycidol, and it can be easily recovered and reused. Under the reaction conditions of a DMC–glycerol molar ratio of 2, catalyst–glycerol weight ratio of 3%, reaction time of 90 min, and temperature of 80–92 °C, the conversion of glycerol and the selectivity to glycidol reached 94.7% and 80.7%, respectively. Activity tests of the catalyst after exposure to the air showed that, to a certain extent, the NaAlO2 catalyst is tolerant to water and carbon dioxide, which makes the present system a practically interesting process for glycidol synthesis.
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Green Chemistry

Green Chemistry provides a unique forum for the publication of innovative research on the development of alternative green and sustainable technologies. The scope of Green Chemistry is based on, but not limited to, the definition proposed by Anastas and Warner (Green Chemistry: Theory and Practice, P T Anastas and J C Warner, Oxford University Press, Oxford, 1998). Green chemistry is the utilisation of a set of principles that reduces or eliminates the use or generation of hazardous substances in the design, manufacture and application of chemical products. Green Chemistry is at the frontiers of this continuously-evolving interdisciplinary science and publishes research that attempts to reduce the environmental impact of the chemical enterprise by developing a technology base that is inherently non-toxic to living things and the environment. Submissions on all aspects of research relating to the endeavour are welcome. The journal publishes original and significant cutting-edge research that is likely to be of wide general appeal. To be published, work must present a significant advance in green chemistry. Papers must contain a comparison with existing methods and demonstrate advantages over those methods before publication can be considered. For more information please see this Editorial. Coverage includes the following, but is not limited to: Design (e.g. biomimicry, design for degradation/recycling/reduced toxicity…) Reagents & Feedstocks (e.g. renewables, CO2, solvents, auxiliary agents, waste utilization…) Synthesis (e.g. organic, inorganic, synthetic biology…) Catalysis (e.g. homogeneous, heterogeneous, enzyme, whole cell…) Process (e.g. process design, intensification, separations, recycling, efficiency…) Energy (e.g. renewable energy, fuels, photovoltaics, fuel cells, energy storage, energy carriers…) Applications (e.g. electronics, dyes, consumer products, coatings, pharmaceuticals, preservatives, building materials, chemicals for industry/agriculture/mining…) Impact (e.g. safety, metrics, LCA, sustainability, (eco)toxicology…) Green chemistry is, by definition, a continuously-evolving frontier. Therefore, the inclusion of a particular material or technology does not, of itself, guarantee that a paper is suitable for the journal. To be suitable, the novel advance should have the potential for reduced environmental impact relative to the state of the art. Green Chemistry does not normally deal with research associated with 'end-of-pipe' or remediation issues.










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